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Novel catalyst for hydrogenation of polymer and process for hydrogenating polymer with the catalyst
Novel catalyst for hydrogenation of polymer and process for hydrogenating polymer with the catalyst
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机译:用于聚合物加氢的新型催化剂和用该催化剂加氢聚合物的方法
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摘要
A hydrogenation catalyst consisting essentially of (A) at least one bis(cyclopentadienyl)titanium compound represented by the formula (1): wherein R¹ and R², which may be the same or different, represent halogen atoms, hydrocarbon groups, aryloxy groups, alkoxy groups or carbonyl groups, and (B) at least one lithium compound represented by the formula (2):R³O-Li (2)wherein R³ represents a hydrocarbon group, or a reaction mixture of an organolithium compound with an alcoholic or phenolic hydroxyl group-containing compound, the (A) component/the (B) component molar ratio being 1/0.5 to 1/20, and optionally (C) at least one reducing organometallic compound selected from the group consisting of aluminum compounds, zinc compounds and magnesium compounds, the (A) component/the (C) component molar ratio being 1/0.5 to 1/20. The above hydrogenation catalyst is effectively applied to the hydrogenation of a polymer having olefinic double bonds to produce a hydrogenated polymer having a high degree of hydrogenation at a high hydrogenation rate with a high reproducibility.
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