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Potassium hexatitanate fibers, and composite material containing said fibers

机译:六钛酸钾纤维以及包含该纤维的复合材料

摘要

Potassium hexatitanate fibers having a tunnel struc­ture and a free potassium content of 5 ppm or less can be produced by mixing together a titanium containing compound and a potassium containing compound in a ratio represented by the formula K₂O·nTiO₂ (wherein n = from 2 to 4); firing the mixture at 900 to 1,200°C to produce mass of potassium titanate fibers; dipping the mass of product in either cold or hot water to disintegrate the mass of potassium titanate fibers into individual single fibers; adding an acid to the slurry to adjust the pH value to 9.3 - 9.7, thereby changing the composition of the potassium titanate fibers so that the molar ratio of TiO₂/K₂O is in the range of from 5.95 to 6.00; heating the fibers at 950 to 1,150°C for 1 hour or more; and washing the fibers with an acid. The potassium hexatitanate fibers, which have a minimal free potassium content, i.e., 5 ppm or less, can be suitably used as a reinforcing material for polyester thermoplastic resins, polyphenylene sulfide resins, liquid crystal polymers, aluminum alloys, magnesium alloys and so forth, all of which are easily affected by free potassium.
机译:具有隧道结构且游离钾含量为5ppm或更低的六钛酸钾纤维可以通过将含钛化合物和含钾化合物以式K 2 O·nTiO 2(其中n = 2至4)表示的比例混合在一起来制备。 );在900至1200℃下烧制该混合物以产生大量的钛酸钾纤维。将产品块浸入冷水或热水中,以将钛酸钾纤维块分解成单个单纤维;向浆液中加入酸以将pH值调节至9.3-9.7,从而改变钛酸钾纤维的组成,以使TiO 2 / K 2 O的摩尔比为5.95-6.00。在950〜1150℃下加热1小时以上。然后用酸清洗纤维。具有最小的游离钾含量,即5ppm或更少的六钛酸钾纤维,适合用作聚酯热塑性树脂,聚苯硫醚树脂,液晶聚合物,铝合金,镁合金等的增强材料,所有这些都容易受到游离钾的影响。

著录项

  • 公开/公告号EP0323012B1

    专利类型

  • 公开/公告日1993-05-19

    原文格式PDF

  • 申请/专利权人 TITAN KOGYO KABUSHIKI KAISHA;

    申请/专利号EP19880310518

  • 发明设计人 HARADA HIDEFUMI;INOUE YASUO;

    申请日1988-11-09

  • 分类号C01G23/00;

  • 国家 EP

  • 入库时间 2022-08-22 05:06:33

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