PURPOSE:To obtain a polyamide elastomer which is flexible, tough and transparent and suitable for hoses, tubes, etc., by condensing a carboxyl group-terminated polycapramide through dehydration, by a specified production process with polytetramethylene ether glycol. CONSTITUTION:A carboxyl group-terminated polycapramide (A), number-average MW of 500-5,000, obtained from a 4-20C aliphatic dicarboxylic acid, alicyclic dicarboxylic acid or aromatic dicarboxylic acid (e.g., terephthalic acid) and caprolactam is condensed with polytetramethylene ether glycol (B) of a number- average MW of 800-5,000 at a weight ratio of component A to component B of 10:90-60:40 through dehydration. In this way, a transparent polyamide elastomer of a polyamide partition ratio of 0.7-1.3, a Shore hardness of 60A-50D, a tensile strength at break =150kg/cm2 and a haze number at a thickness of 1mm=75% can be obtained.
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机译:用途:通过将羧基封端的聚己酰胺经脱水缩合,然后使用聚四亚甲基醚二醇进行特定生产工艺,从而获得柔软,坚韧和透明且适用于软管,管等的聚酰胺弹性体。组成:由4-20C脂肪族二羧酸,脂环族二羧酸或芳族二羧酸(例如对苯二甲酸)和己内酰胺得到的羧基端基聚己酰胺(A),数均分子量为500-5,000通过脱水,组分A与组分B的重量比为10:90-60:40的数均分子量为800-5,000的乙二醇(B)。这样,聚酰胺分配比为0.7-1.3,肖氏硬度为60A-50D,断裂拉伸强度≥150kg/ cm 2且雾度值为1mm≤2的透明聚酰胺弹性体。可以得到75%。
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