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MIXED BODY SUITABLE FOR ELECTRODE MATERIAL FOR SOLID ELECTROLYTE TYPE FUEL CELL, AND ELECTRODE FOR SOLID ELECTROLYTE TYPE FUEL CELL

机译:适用于固体电解质型燃料电池的电极材料的混合体和适用于固体电解质型燃料电池的电极的混合体

摘要

PURPOSE:To improve electric performance of an electrode for a solid electrolyte type fuel cell (SOFC), by mixing a specific oxide solid solution with zirconium at a fixed ratio. CONSTITUTION:In the mixed body of an oxide solid solution and cubic and/or solution has main components of magnesium oxide and nickel oxide, the magnesium oxide is made to have 5mol or more and 25mol% or less to total mol quantity of the magnesium oxide and the nickel oxide, and the remainder is the nickel oxide. In cubic and/or tetragonal zirconium, its mixed quantity is made 35mol% or less to the total mol quantity of the mixed body. An SOFC electrode is manufactured by a usual method with the mixed body as material. At that time, it is required to reduce the oxide solid solvent to deposit Ni. Consequently electronic conductivity by Ni is given, and concurrently thermal expansion coefficient approaches that of the cubic oxide zirconium, usually used as solid electrolyte material, in the zirconium oxide, and ion conductivity is given.
机译:目的:通过将特定的氧化物固溶体与锆以固定比例混合,以提高用于固体电解质型燃料电池(SOFC)的电极的电性能。组成:在氧化物固溶体和立方和/或溶液的主要成分为氧化镁和氧化镍的混合体中,使氧化镁占氧化镁总摩尔量的5mol%以上至25mol%以下氧化镍,其余为氧化镍。在立方和/或四方锆中,其混合量相对于混合体的总摩尔量为35摩尔%以下。通过通常的方法以混合体为材料来制造SOFC电极。那时,需要还原氧化物固体溶剂以沉积Ni。因此,给出了通过Ni的电子传导性,并且同时热膨胀系数接近了在氧化锆中通常用作固体电解质材料的立方氧化物锆的热膨胀系数,并且给出了离子传导性。

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