首页> 外国专利> Modified polyarylene ether moulding materials - contain 5-50 wt. per cent block co-polycondensate contg. polyarylene ether blocks and thermotropic polyester blocks

Modified polyarylene ether moulding materials - contain 5-50 wt. per cent block co-polycondensate contg. polyarylene ether blocks and thermotropic polyester blocks

机译:改性聚亚芳基醚成型材料-包含5-50 wt。百分比的共缩聚物续量。聚亚芳基醚嵌段和热致聚酯嵌段

摘要

Moulding materials (I) are claimed, contg. (A) 50-95 wt.% polyarylene ether, (B) 5-50 wt.% block copolycondensate of (B1) polyarylene ether blocks and (B2) thermotropic polyester blocks, and (C) 0-40 wt.% additives etc.. Pref. (I) contains 70-95 wt.% (A), 5-30 wt.% (B) comprising 2-50 wt.% (B1) blocks and 50-98 wt.% (B2) blocks, and 0-40 wt.% (C). (A) is a polymer with repeating units of formula (II), or a statistical copolymer or block copolymer thereof; t, q = 0, 1, 2 or 3; T, Q = SO2, O, S, CO, N=N, SO, -RaC=CRb-, direct bond or CRcRd (with Ra, Rb = H or 1-6C alkyl and Rc, Rd = H, 1-6C alk(ox)yl or aryl opt. substd. with F and/or Cl); Z = SO2, CO, -RaC=CRb-, SO or N=N; Ar, Ar1 = 6-14C aryl, opt. substd. 1-8C alkyl, 6-20C aryl, 1-8C alkoxy or halo. USE/ADVANTAGE - Used for the prodn. of fibres, film and moulded prods. (claimed). Also claimed are fibres, film and moulded prods. obtd. from (I). Compared with prior-art mixts. of polyacrylene ethers and thermotropic polyesters, (I) have a better balance of good flow properties and mechanical properties, esp. high heat distortion pt. and good rigidity; (I) are therefore suitable for the prodn. of fine-structured mouldings, esp. for electrical and electronic components.
机译:要求保护模制材料(I),续。 (A)50-95 wt。%的聚亚芳基醚,(B)5-50 wt。%的(B1)聚亚芳基醚嵌段和(B2)热致性聚酯嵌段的嵌段共缩聚物,以及(C)0-40 wt。%的添加剂等..首选(I)包含70-95 wt。%(A),5-30 wt。%(B),其中包含2-50 wt。%(B1)嵌段和50-98 wt。%(B2)嵌段,以及0-40重量%(C)。 (A)为具有式(II)的重复单元的聚合物,或其统计共聚物或嵌段共聚物。 t,q = 0、1、2或3; T,Q = SO2,O,S,CO,N = N,SO,-RaC = CRb-,直接键或CRcRd(其中Ra,Rb = H或1-6C烷基,Rc,Rd = H,1-6C烷基(氧)基或芳基,优选用F和/或Cl取代); Z = SO 2,CO,-RaC = CRb-,SO或N = N; Ar,Ar1 = 6-14C芳基,opt。取代1-8C烷基,6-20C芳基,1-8C烷氧基或卤素。 USE / ADVANTAGE-用于产品。纤维,薄膜和模压产品。 (声称)。还要求保护的是纤维,薄膜和模制产品。 t。来自(I)。与现有技术的混合料相比。 (I)较好地平衡了良好的流动性和机械性能,尤其是(I)。高热变形点刚性好; (I)因此适合该产品。精细结构的模具,特别是用于电气和电子组件。

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