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1,6-diazaspiro 4,4 nonane-2,7-dione derivatives.

机译:1,6-二氮杂螺[4,4]壬烷-2,7-二酮衍生物。

摘要

A 1,6-diazaspiro[4,4]nonane-2,7-dione derivative having the formula I: X @B-Y@P-Y @@@@B-X (I) in which B has the formula II: CHEM wherein a) Z1, Z2, Z3, Z4 are independently - C(Z min )2 in which Z min independently is hydrogen or C1-4 alkyl, or - such that two adjacent Z atoms form part of a benzene ring; b) each R is independently a bivalent group of the formula III or IV: CHEM wherein A is a substituent replacing hydrogen selected independently from a C1-4 alkyl or halogen atom, n independently is 0, 1 or 2 and the free valence bond of C* is linked with a ring nitrogen atom of the spirodilactam of the formula II; c) m /= 0; d) each X independently is hydrogen or a glycidyl-, acrylyl-, methacrylyl-, allyl- or propargyl group, with the proviso that when X is acrylyl, methacrylyl, allyl or propargyl then m is 0; e) Y is 2-hydroxy-1,3-propadiyl; f) each P independently is a divalent radical derived from a dihydric aromatic alcohol; g) p is on average of from 0 to 3; with the proviso that when R is a bivalent group of the formula III and simultaneously Z2 and Z3 are each CH2 and simultaneously Z1 and Z4 are each independently hydrogen or a C1-4 alkyl, then each X is not hydrogen or glycidyl.
机译:具有式I的1,6-二氮杂螺[4,4]壬烷-2,7-二酮衍生物:(I)其中X具有式II: )Z 1,Z 2,Z 3,Z 4独立地是-C(Z min)2,其中Z min独立地是氢或C 1-4烷基,或-使得两个相邻的Z原子形成苯环的一部分; b)每个R独立地是式III或IV的二价基团:,其中A是取代氢的取代基,该取代基独立地选自C 1-4烷基或卤素原子,n独立地为0、1或2且自由价C *的键与式II的螺二内酰胺的环氮原子连接; c)m> / = 0; d)每个X独立地为氢或缩水甘油基,丙烯酰基,甲基丙烯酰基,烯丙基或炔丙基,条件是当X为丙烯酰基,甲基丙烯酰基,烯丙基或炔丙基时,m为0; e)Y为2-羟基-1,3-丙二基; f)每个P独立地是衍生自二元芳族醇的二价基团; g)p平均为0到3;前提是当R是式III的二价基团并且Z 2和Z 3分别是CH 2且同时Z 1和Z 4各自独立地是氢或C 1-4烷基时,则每个X都不是氢或缩水甘油基。

著录项

  • 公开/公告号DE68913108T2

    专利类型

  • 公开/公告日1994-09-01

    原文格式PDF

  • 申请/专利权人 SHELL INT RESEARCH NL;

    申请/专利号DE1989613108T

  • 发明设计人 WANG PEN CHUNG US;

    申请日1989-09-15

  • 分类号C07D487/10;C08G59/06;C07D519/00;C08G59/26;

  • 国家 DE

  • 入库时间 2022-08-22 04:35:16

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