首页> 外国专利> Poly free sulfurized compositions of unsaturated fatty substances and / or multiply unsaturated esters of acids and, if appropriate, olefins, their preparation and use as lubricant additives means.

Poly free sulfurized compositions of unsaturated fatty substances and / or multiply unsaturated esters of acids and, if appropriate, olefins, their preparation and use as lubricant additives means.

机译:不饱和脂肪物质和/或酸和(如果适用)烯烃的多种不饱和酯的多聚游离硫化组合物,其制备方法和用作润滑剂添加剂的手段。

摘要

The invention relates to compositions polysulfurized of fatty acids or esters of unsaturated (poly) obtained by a process which comprises in particular: - a step 1 in which is reacted, an unsaturated fatty substance and / or an ester of unsaturated acids (poly) in the presence or absence of a monoolefin aliphatic with, at least one compound chosen from among the monochloride and sulphur dichloride, thus forming an addition product, or "adduct"; - a step 2 in which is reacted, the hydrogen sulphide and / or a mercaptan with an alkali metal hydroxide or ammonium hydroxide in an aliphatic monoalcohol substantially anhydrous; - a step 3 in which are placed in contact with the adduct and possibly one monohalogenated hydrocarbon compound, with, the alcoholic solution obtained at the end of step 2; - a step 4 in which the monoalcohol is removed by distillation under reduced pressure. / p & & p & these compositions are used as additives for lubricants, mineral or synthetic.
机译:本发明涉及通过以下方法获得的脂肪酸或不饱和(聚)酯的多硫化组合物,该方法特别包括:-在步骤1中,使不饱和脂肪物质和/或不饱和酸(聚)的酯反应。单烯烃脂肪族与至少一种选自一氯化物和二氯化硫的化合物的存在或不存在,从而形成加成产物或“加合物”; -步骤2,其中硫化氢和/或硫醇与碱金属氢氧化物或氢氧化铵在基本上无水的脂肪族一元醇中反应; -步骤3,其中使之与加合物和可能的一种单卤代烃化合物接触,使之与在步骤2结束时获得的醇溶液接触; -步骤4,其中在减压下通过蒸馏除去一元醇。 & &这些组合物用作矿物或合成润滑剂的添加剂。

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