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Polysulfide compositions from unsaturated fatty elements and/or (poly)unsaturated esters from acids and from olefins, optionally their preparation and their utilisation as lubricant additives

机译:来自不饱和脂肪元素和/或酸和烯烃的(或)(不饱和)酯的多硫化物组合物,可选地其制备方法及其作为润滑剂添加剂的用途

摘要

Polysulphide compositions of fatty substances or esters of (poly)unsaturated acids obtained by a process which comprises especially: - a stage (1) in which at least one unsaturated fatty substance and/or at least one ester of poly(unsaturated) carboxylic acid is/are reacted in the presence or absence of an aliphatic monoolefin, with at least one compound chosen from sulphur monochloride and dichloride, thus forming an addition product or adduct; - a stage (2) in which hydrogen sulphide and/or a mercapton is/are reacted with an alkali metal hydroxide or ammonium hydroxide in a substantially anhydrous aliphatic monoalcohol; - a stage (3) in which the said adduct and optionally a monohalogenated hydrocarbon compound are brought into contact with the alcoholic solution obtained at the end of stage (2); - a stage (4) in which the monoalcohol is removed by distillation under reduced pressure. These compositions are employed as additives for inorganic or synthetic lubricants.
机译:通过以下方法获得的脂肪物质或(多)不饱和酸的酯的多硫化物组合物,所述方法特别包括:-步骤(1),其中至少一种不饱和脂肪物质和/或至少一种多(不饱和)羧酸的酯是在有或没有脂族单烯烃的情况下与至少一种选自一氯化硫和二氯化硫的化合物反应,从而形成加成产物或加合物; -步骤(2),其中使硫化氢和/或硫醇与碱金属氢氧化物或氢氧化铵在基本上无水的脂肪族一元醇中反应; -步骤(3),其中使所述加合物和任选的单卤代烃化合物与在步骤(2)结束时获得的醇溶液接触; -步骤(4),其中通过减压蒸馏除去一元醇。这些组合物用作无机或合成润滑剂的添加剂。

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