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Process for automatically controllable reduction of the nitrite content of nitrite-containing aqueous solutions to values below 1 mg/1

机译:将亚硝酸盐水溶液中亚硝酸盐含量自动降低至1 mg / 1以下的方法

摘要

Reduction of the nitrite content of aqueous solutions by treatment with hydrogen peroxide in the acidic pH range can be controlled by measurement of the redox potential. Contrary to the teaching of the prior art, addition of the hydrogen peroxide in the process according to the invention is terminated not at the highest redox potential, but only after lowering of the potential to a value of 650.+-.10 mV. In this way, nitrite contents below 1 mg/l can be obtained even when the solutions additionally contain fluctuating amounts of various compounds oxidizable by H.sub.2 O.sub.2.
机译:通过在酸性pH范围内用过氧化氢处理来减少水溶液中亚硝酸盐含量可以通过测量氧化还原电势来控制。与现有技术的教导相反,在根据本发明的方法中的过氧化氢的添加不是在最高氧化还原电位时才终止,而是仅在将电位降低至650.±0.1mV的值之后才终止。以这种方式,即使溶液另外含有波动量的可被H 2 O 2氧化的各种化合物,也可获得低于1 mg / l的亚硝酸盐含量。

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