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Light-sensitive composition containing diazo resin, polyurethane resin and fluorine atom-containing copolymer surfactant

机译:包含重氮树脂,聚氨酯树脂和含氟原子的共聚物表面活性剂的光敏组合物

摘要

A light-sensitive composition comprises a light-sensitive diazo resin, a polymer binder and a fluorine atom-containing surfactant, wherein the polymer binder is a polyurethane resin having acidic hydrogen atom- containing substituents and comprising structural units derived from a diol represented by the following general formula (I); and the fluorine atom-containing surfactant is a copolymer of (i) an acrylate or methacrylate having a fluoroaliphatic group which has a carbon atom number of 3 to 20 and a fluorine atom content of not less than 30% by weight and in which at least three terminal carbon atoms are completely fluorinated, with (ii) poly(oxyalkylene) acrylate or poly(oxyalkylene) methacrylate, the copolymer containing the fluoroaliphatic group- containing acrylate or methacrylate units in an amount ranging from 35 to 50% by weight on the basis of the weight of the copolymer and the copolymer having has a molecular weight ranging from 20,000 to 100, 000:PPHO--(CH.sub.2 CH.sub.2 O).sub.n --H (I)P Pwherein n is an integer of not less than 3. The light-sensitive composition can provide a PS plate having sufficient developability with an exhausted developer and can provide a lithographic printing plate having good printing durability and excellent ink receptivity during printing even after storing under high temperature and humidity conditions or after being exposed to light.
机译:光敏组合物包含光敏重氮树脂,聚合物粘合剂和含氟原子的表面活性剂,其中所述聚合物粘合剂是具有酸性含氢原子取代基并且包含衍生自由以下物质代表的二醇的结构单元的聚氨酯树脂。遵循通式(I);含氟原子的表面活性剂是(i)具有碳原子数为3〜20且氟原子含量为30重量%以上的氟代脂族基的丙烯酸酯或甲基丙烯酸酯的共聚物。三个末端碳原子被(ii)聚(氧化烯基)丙烯酸酯或聚(氧化烯基)甲基丙烯酸酯完全氟化,该共聚物中含氟代脂族基团的丙烯酸酯或甲基丙烯酸酯单元的含量为35至50%(重量)共聚物的重量和分子量范围为20,000至100,000的共聚物:-P> -HO-(CH.sub.2 CH.sub.2 O)n- H(I)P,其中n为不小于3的整数。该光敏组合物可以提供用完的显影剂具有足够的显影性的PS板,并且可以提供具有良好的印刷耐久性和稳定性的平版印刷版。即使在室温下保存,在打印过程中也具有出色的吸墨性高温高湿条件下或暴露于阳光下。

著录项

  • 公开/公告号US5340685A

    专利类型

  • 公开/公告日1994-08-23

    原文格式PDF

  • 申请/专利权人 FUJI PHOTO FILM CO. LTD.;

    申请/专利号US19930040615

  • 发明设计人 TOSHIYUKI SEKIYA;

    申请日1993-03-31

  • 分类号G03F7/021;

  • 国家 US

  • 入库时间 2022-08-22 04:31:14

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