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METHOD OF SYNTHESIS OF AMINOPHENYLPERFLUOROALKYLSULFIDES

机译:合成氨基苯酚全氟烷基酯的方法

摘要

FIELD: chemical technology. SUBSTANCE: synthesis is carried out by treatment of corresponding dinitrodiphenyldisulfides with alkaline or alkaline-earth metal in liquid ammonia and the following UV-irradiation of solution formed together with perfluoroalkyl iodide added to it. Under these conditions the yield of the end product is increased from 50-60 to 75-85%. Stages of isolation and purification of hazard aminothiophenols were excluded. EFFECT: increased yield of products, development of universal and safety method of synthesis. 2 tbl
机译:领域:化学技术。物质:通过在液氨中用碱金属或碱土金属处理相应的二硝基二苯基二硫化物,然后将形成的溶液与全氟烷基碘一起进行紫外线照射,进行合成。在这些条件下,最终产物的产率从50-60增加到75-85%。排除了危险氨基硫酚的分离和纯化步骤。效果:提高产品产量,开发通用且安全的合成方法。 2汤匙

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