where R1-CH3, C2H5; R2-CH3, C2H5,. Synthesis of substituted triazines is carried out by chlorine exchange for alkylmercapto-group in compounds of the general formulas CH(CH3)2; R3-C2H5, CH(CH3)2, C(CH3)3, (II) and -SNa (III) in the presence of catalyst of the formula (IV) RаRбRвRгN6·X- where Ra-C2H5, н-C4H9;; Rб-C2H5, н-C3H7,, н-C4H9; Rв-C2H5,, cyclohexyl; н-C3H7, н-C4H9,, mixture of Rг-н-C4H9, н-С10H33,; X bromine, iodine. Catalyst is used at concentration 0.5-3 wt. -% of initial (II) н-C16H33-н-С20H42;, and process is carried out in aqueous medium at 80-93 C. The yield of substituted triazines is 99-97% the content of the basic substance is up to 99.3% Process is carried out at lower temperature and under atmospheric pressure as compared with known method. Synthesized compounds were used as components of herbicides. EFFECT: simplified process, decreased energy consumption. 3 tbl"/>
METHOD OF SYNTHESIS OF 2-ALKYLTHIO-4,6-BIS-(ALKYLAMINO)-1,3,5-TRIAZINES
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METHOD OF SYNTHESIS OF 2-ALKYLTHIO-4,6-BIS-(ALKYLAMINO)-1,3,5-TRIAZINES
METHOD OF SYNTHESIS OF 2-ALKYLTHIO-4,6-BIS-(ALKYLAMINO)-1,3,5-TRIAZINES
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机译：合成2-烷基噻-4,6-BIS-（烷基氨基）-1,3,5-三嗪的方法
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FIELD: organic chemistry. SUBSTANCE: products: substituted triazines of the general formula (I) where R1-CH3, C2H5; R2-CH3, C2H5,. Synthesis of substituted triazines is carried out by chlorine exchange for alkylmercapto-group in compounds of the general formulas CH(CH3)2; R3-C2H5, CH(CH3)2, C(CH3)3, (II) and -SNa (III) in the presence of catalyst of the formula (IV) RаRбRвRгN6·X- where Ra-C2H5, н-C4H9;; Rб-C2H5, н-C3H7,, н-C4H9; Rв-C2H5,, cyclohexyl; н-C3H7, н-C4H9,, mixture of Rг-н-C4H9, н-С10H33,; X bromine, iodine. Catalyst is used at concentration 0.5-3 wt. -% of initial (II) н-C16H33-н-С20H42;, and process is carried out in aqueous medium at 80-93 C. The yield of substituted triazines is 99-97% the content of the basic substance is up to 99.3% Process is carried out at lower temperature and under atmospheric pressure as compared with known method. Synthesized compounds were used as components of herbicides. EFFECT: simplified process, decreased energy consumption. 3 tbl
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机译：领域：有机化学。物质：产品：具有通式（I）的取代的三嗪其中R 1 -CH 3 ，C 2 H 5 ; R 2 -CH 3 ，C 2 H 5 ，取代的三嗪的合成是通过氯交换通式CH（CH 3 ） 2 的化合物中的烷基巯基进行的; R 3 -C 2 H 5 ，CH（CH 3 ） 2 ， C（CH 3 ） 3 ，（II）和<图像文件=“ 00000004.GIF” he =“ 10” id =“ imag0.4” imgContent =“ undefined在式（IV）的催化剂存在下，“ imgFormat =“ GIF” wi =“ 53” />-SNa（III）R а R б R в R г N 6 ·X -其中R a -C 2 H 5 ，н-C 4 H 9 ;; R б -C 2 H 5 ，н-C 3 H 7 ， ，н-C 4 H 9 ; R – -C 2 H 5 ，环己基; н-C 3 H 7 ，н-C 4 H 9 ，R г的混合物-н-C 4 H 9 ，н-С 10 H 33 ,; X溴，碘。催化剂的使用浓度为0.5-3重量％。 -初始（II）н-C 16 H 33 -н-С 20 H 42 的百分比;并在含水介质中于80-93 C下进行处理。取代的三嗪的产率为99-97％，碱性物质的含量最高为99.3％。与已知方法相比，该方法在较低的温度和大气压下进行方法。合成的化合物用作除草剂的成分。效果：简化了工艺，降低了能耗。 3汤匙
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