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Process for the preparation of alkoxylation products in the presence of mixed hydroxides modified with additives

机译:在添加剂改性的混合氢氧化物存在下制备烷氧基化产物的方法

摘要

PCT No. PCT/EP94/02195 Sec. 371 Date Jan. 29, 1996 Sec. 102(e) Date Jan. 29, 1996 PCT Filed Jul. 5, 1994 PCT Pub. No. WO95/04024 PCT Pub. Date Feb. 9, 1995Alkoxylation products are prepared by reacting compounds having active hydrogen atoms with C2-C4-alkylene oxides in the presence of a mixed hydroxide built up of polycations and modified with additives and having the general formula I or II[M(II)1-xM(III)x(OH)2]Ax/nxm L(I)[LiAl2(OH)6]A1/nxm L(II)where M(II) is at least one divalent metal ion, M(III) is at least one trivalent metal ion, A is at least one inorganic anion and L is an organic solvent or water, n is the valence of the inorganic anion A or in the case of a plurality of anions A is their mean valence and x can assume a value of from 0.1 to 0.5 and m can assume a value of from 0 to 10, as alkoxylation catalyst, wherein the mixed hydroxide contains additives.
机译:PCT号PCT / EP94 / 02195秒371日期1996年1月29日102(e),1996年1月29日,PCT,1994年7月5日提交,PCT Pub。 WO95 / 04024 PCT公开日期1995年2月9日,烷氧基化产品是通过在具有聚阳离子和添加剂修饰的通式I或II [M(II)的混合氢氧化物的存在下,将具有活泼氢原子的化合物与C2-C4-环氧烷烃反应制得的)1-xM(III)x(OH)2] Ax / nxm L(I)[LiAl2(OH)6] A1 / nxm L(II)其中M(II)是至少一个二价金属离子M(III )是至少一种三价金属离子,A是至少一种无机阴离子,L是有机溶剂或水,n是无机阴离子A的化合价,或者在多个阴离子的情况下A是它们的平均化合价,x作为烷氧基化催化剂,α-α可以为0.1-0.5,m为0-10,其中混合的氢氧化物包含添加剂。

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