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Catalysts based on metallic oxides, with high dispersion, comprising in particular zirconia, their manufacture and their applications.

机译:基于金属氧化物的,具有高分散性的催化剂,特别是氧化锆,其制备方法及其应用。

摘要

Catalyst including at least one zirconium oxide, characterised in that at least 85 % of its weight consists of a thermally stable support with a specific surface greater than or equal to 150 m2/g containing from 60 to 99 % by weight of at least one zirconium oxide and from 40 to 1 % by weight of at least one metal oxide of at least one metal chosen from the group consisting of the metals of groups V, VI and VII, noble metals such as ruthenium, osmium, rhodium, iridium and uranium, and the elements phosphorus, arsenic and sulphur, the support being obtained by the molten salts technique by introducing this mixture of oxides into a eutectic mixture of alkali metal nitrates or sulphates which, after dehydration, is maintained between 250 and 550 DEG C, for 30 minutes to 5 hours.
机译:包含至少一种氧化锆的催化剂,其特征在于其至少85%的重量由热稳定的载体组成,所述载体的比表面积大于或等于150m 2 / g,包含60%至99%(重量)的氧化锆。至少一种氧化锆和按重量计从40%至1%的至少一种金属氧化物,选自至少一种金属,该金属选自第V,VI和VII组金属,贵金属,如钌,,铑,铱通过将盐的混合物引入碱金属硝酸盐或硫酸盐的低共熔混合物中,然后通过脱水将氧化混合物保持在250至550℃之间,通过熔融盐技术获得载体,其中的元素包括磷,铀和磷,砷和硫。 ,持续30分钟到5小时。

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