首页> 外国专利> Preparation of flexible, soft polyurethane foams having viscoelastic, structure-borne soundproofing properties, and polyoxyalkylene-polyol mixtures which can be used for this purpose

Preparation of flexible, soft polyurethane foams having viscoelastic, structure-borne soundproofing properties, and polyoxyalkylene-polyol mixtures which can be used for this purpose

机译:制备具有粘弹性,结构传递的隔音性能的软质聚氨酯软泡沫塑料和可用于此目的的聚氧化烯-多元醇混合物

摘要

The present invention relates to a process for the preparation of flexible, soft polyurethane foams having viscoelastic, structure-borne soundproofing properties in a temperature range of from -20° C. to + 80° C. by reactingPPa) a polyoxyalkylene-polyol mixture containingPPai) block polyoxypropylene- polyoxyethylene-polyol mixture having a hydroxyl number of from 14 to 65 and containing from 2 to 9% by weight of terminal ethylene oxide units, based on the weight of the polyoxypropylene units, prepared by anionic polymerization, at elevated temperatures, of 1,2-propyleneoxide onto an initiator molecule mixture having a mean functionality of from 2.3 to 2.8, comprising water and glycerol and/or trimethylolpropane, and polymerization of acylene oxide onto the resultant polyoxypropylene adduct, andPPaii) one or more difunctional and/or trifunctional polyoxypropylene-polyoxyethylene-polyol containing from 60 to 85% by weight of oxyethylene units, based on the total weight of polymerized alkylene oxide units, and having a hydroxyl number of from 20 to 80, andPPb) if desired low-molecular-weight chain extenders withPPc) organic and/or modified organic polyisocyanates in the presence ofPP d) catalysts, PPe) blowing agents, preferably water, and, if desired, PPf) auxiliaries and/or additives,PPand to the polyoxyalkylene-polyol mixtures (a) which can be used for this purpose.
机译:本发明涉及一种制备软的,柔软的聚氨酯泡沫的方法,该软的聚氨酯泡沫通过使P a与P a发生反应而在-20℃至+ 80℃的温度范围内具有粘弹性的结构承载的隔音性能。 )包含(P> )的聚氧化烯-多元醇混合物,基于重量计,羟值为14至65且含有2至9%的末端环氧乙烷单元的嵌段聚氧化丙烯-聚氧化乙烯-多元醇混合物在高温下通过阴离子聚合将1,2-环氧丙烷制备到平均官能度为2.3至2.8的包含水和甘油和/或三羟甲基丙烷的引发剂分子混合物上制备1,2,2-环氧丙烷,并将环氧丙烷聚合到所得的聚氧丙烯加合物和 aii)一种或多种二官能和/或三官能的聚氧丙烯-聚氧乙烯-多元醇,其包含基于pol的总重量为60-85%的氧乙烯单元聚合的环氧烷烃单元,其羟基数为20至80,并且如果需要的话具有

b)与> c)有机和/或改性的有机多异氰酸酯的低分子量扩链剂在(P)P)d)催化剂,

P> e)发泡剂,优选水和(如果需要)

P)助剂和/或添加剂的存在下P和可用于该目的的聚氧化烯-多元醇混合物(a)。

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