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Preparation of concentrated aqueous solution of anionic azo dye

机译:阴离子偶氮染料浓水溶液的制备

摘要

PCT No. PCT/EP91/01830 Sec. 371 Date Mar. 26, 1993 Sec. 102(e) Date Mar. 26, 1993 PCT Filed Sep. 25, 1991 PCT Pub. No. WO92/06140 PCT Pub. Date Apr. 16, 1992.If highly concentrated aqueous solutions of azo dyes are prepared directly by diazotization and coupling reactions, appreciable difficulties generally result as a consequence of the fact that the diazotization and coupling reactions give rise to viscous phases which lead to stirring problems in the reaction apparatus used, which in turn results in an incomplete synthesis. The novel process for preparing concentrated aqueous dye solutions of an anionic dye in an aqueous medium overcomes this disadvantage by carrying out the diazotization of the aromatic amine diazo component and/or the coupling reaction between the diazonium salt and the coupling component in the presence of an auxiliary which exerts a viscosity-reducing effect on pasty phases. Examples of such auxiliaries are optionally alkyl-substituted naphthalenesulfonic acid-formaldehyde condensation products, ligninsulfonates, polyacrylates and copolymers of maleic anhydride and methacrylic acid or acrylic acid.
机译:PCT号PCT / EP91 / 01830秒371日期1993年3月26日第102(e),1993年3月26日,PCT,1991年9月25日提交,PCT Pub。 WO92 / 06140 PCT公开日期:1992年4月16日。如果直接通过重氮化和偶合反应制备高浓度的偶氮染料水溶液,由于重氮化和偶合反应会产生粘稠相,从而导致搅拌问题,因此通常会造成明显的困难。在所使用的反应装置中,这反过来导致合成不完全。通过在芳族胺存在下进行芳族胺重氮组分的重氮化和/或重氮盐与偶合组分之间的偶合反应,制备在水性介质中阴离子染料的浓染料水溶液的新方法克服了这一缺点。在糊状相中具有降低粘度作用的助剂。这种助剂的例子是任选的烷基取代的萘磺酸-甲醛缩合产物,木质素磺酸盐,聚丙烯酸酯和马来酸酐与甲基丙烯酸或丙烯酸的共聚物。

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