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Production method of precursor gel of support for catalyst, support for catalyst, production method of catalyst support, catalyst for olefin polymerization, olefin polymerization method by this catalyst
Production method of precursor gel of support for catalyst, support for catalyst, production method of catalyst support, catalyst for olefin polymerization, olefin polymerization method by this catalyst
It contains a minimum of constituents selected from silica, alumina and aluminum phosphate, has a specific surface area of 100 to 800 m 2 / g, crystallization temperature and pupil volume of 700 ° C or higher, and has a specific surface area (SS) and a pupil volume (PV). A support for a catalyst having the following relationship;;SS 〈(PV × 564-358);Alcohol, water, silicon alkoxide and acid are mixed under conditions that prevent gelation or precipitation of silica, and an acidic solution of aluminum compound is added thereto, a gelling agent is added thereto, a gel is recovered, the gel is washed with water, and then washed with an organic liquid. And drying the gel until a powder is obtained, and then calcining the powder.;The olefin polymerization method performed in presence of the catalyst containing chromium in the support body mentioned above.
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机译:它包含选自二氧化硅,氧化铝和磷酸铝的最少成分,比表面积为100至800 m 2 Sup> / g,结晶温度和瞳孔体积为700°C或更高,并且具有比表面积(SS)和瞳孔体积(PV)。具有以下关系的催化剂的载体; SS <(PV×564-358);在防止二氧化硅凝胶化或沉淀的条件下,将醇,水,烷氧基硅和酸混合,并加入铝化合物的酸性溶液向其中添加胶凝剂,回收凝胶,用水洗涤凝胶,然后用有机液体洗涤。干燥凝胶直至获得粉末,然后煅烧粉末。烯烃聚合法在上述载体中在含铬的催化剂存在下进行。
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