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Logically, rheology and are coupled is adapted to that of the resin matrix formulation and their use in the production of preimpregnated fibres and composite materials

机译:从逻辑上讲,流变学和耦合学适合树脂基体配方及其在预浸渍纤维和复合材料生产中的应用

摘要

Chemorheologically viscosity tailored matrix resin formulation for use in forming prepregs and filament wound composite articles and having a specified viscosity profile comprising a curable matrix resin and an effective amount of a reactive resin curing agent reactive at room temperature and a latent resin curing agent substantially non-reactive at room temperature but activated upon heating or radiation such that the matrix resin formulation is adapted upon formulation to have a viscosity sufficiently low enough to enable the matrix resin to impregnate a filament or fiber at room temperature without the necessity for the application of heat or solvent and which, upon standing at room temperature after impregnation into the fiber or filament to form a prepreg composition, rises in viscosity to a viscosity level sufficiently high to prevent substantially any bleed of the matrix resin from winding tension upon spooling of the prepreg yet of sufficiently low enough viscosity to allow the prepreg to tack and drape in order to nestle and set during winding of a filament wound composite article from said prepreg after room temperature storage of the spooled prepreg material, and which matrix resin in the prepreg experiences a reduction in viscosity upon heating the prepreg composition, to a viscosity minimum sufficient low to allow the matrix resin in the heated prepreg to flow and substantially eliminate formation of voids in the winding of a composite article from said prepreg yet not so low as to permit excessive bleeding of the matrix resin from the prepreg and with the continued application of heat to the filament wound composite article to permit the matrix resin in the filament wound composite article to cure to a hardened or gelled state.
机译:用于形成预浸料和长丝缠绕的复合制品的化学流变学定制的基体树脂配方,具有规定的粘度分布,其中包括可固化的基体树脂和有效量的在室温下可反应的反应性树脂固化剂,以及基本不挥发的潜伏性树脂固化剂。在室温下呈反应性,但在加热或辐射时被活化,以使基质树脂制剂在配制时具有足够低的粘度,以使基质树脂能够在室温下浸渍长丝或纤维,而无需施加热量或溶剂,在浸渍到纤维或长丝中以形成预浸料组合物后,在室温下放置时,其粘度升高至足够高的粘度水平,以防止预浸料的卷取时基本上任何基体树脂的渗出缠绕张力。足够低的粘度以允许预浸料的粘性和悬垂性,以便在缠绕的预浸料在室温下储存后,从所述预浸料缠绕长丝缠绕的复合制品时从所述预浸料中嵌套和凝固,并且在加热预浸料组合物时,预浸料中的哪种基体树脂的粘度降低,粘度最低至足够低以允许加热的预浸料中的基体树脂流动并基本消除复合制品在缠绕中由所述预浸料形成的空隙,但又不低至允许基体树脂从预浸料中过量渗出的程度。继续加热加热到缠绕长丝的复合制品,以使缠绕长丝的复合制品中的基体树脂固化成硬化或胶凝状态。

著录项

  • 公开/公告号DE69024319T2

    专利类型

  • 公开/公告日1996-06-20

    原文格式PDF

  • 申请/专利权人 THIOKOL CORP US;

    申请/专利号DE1990624319T

  • 发明设计人 MUMFORD NEAL A US;DECKER OWEN H US;

    申请日1990-10-16

  • 分类号C08J3/00;C08J3/24;C08J5/24;

  • 国家 DE

  • 入库时间 2022-08-22 03:41:43

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