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PROCESS FOR THE SYNTHESIS OF ZEOLITES AND MESOPOROUS SOLIDS FROM A HOMOGENEOUS SOLUTION IN A SEMI-OPEN SYSTEM

机译:半开放系统中均质溶液合成沸石和介孔固体的过程

摘要

The invention relates to a process for synthesizing zeolites based on element (s) T and mesoporous solids based on element (s) T, T being silicon and / or aluminum, comprising the following successive steps: BR/ i) the synthesis of a source reaction medium of homogeneous element (s) T containing: BR/ a) - at least one element source (s) T chosen from the group formed by the solutions basic aqueous silica or silica and alumina and alcoholic solutions of alkyl tetraorthosilicate and trialkoxyaluminium, BR/ b) - optionally at least one structuring agent, BR/ c) - optionally seeds of the phase crystalline desired, BR/ ii) the heating of the reaction medium at a temperature between 20 and 220 deg. C for a period of between a few minutes and a few days, BR/ iii) the controlled-rate injection of at least one chemical agent that allows the generation of the polycondensable species in said medium.
机译:本发明涉及一种合成基于元素T的沸石和基于元素T的介孔固体的方法,其中T为硅和/或铝,包括以下连续步骤:一种均质元素T的源反应介质,其包含:
a)-至少一种元素源T,其选自碱性二氧化硅水溶液或二氧化硅和氧化铝的溶液以及四原硅酸烷基酯的醇溶液和三烷氧基铝,
b)-可选地至少一种结构化剂,
c)-可选地为所需结晶相的晶种,
ii)在20至200之间的温度下加热反应介质220度在几分钟和几天之间的一段时间内,
iii)控制速率注射至少一种化学试剂,该化学试剂允许在所述介质中产生可缩聚性物质。

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