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Use of Chelex-100 for selectively removing Y-90 from its parent Sr-90

机译:Chelex-100用于从其母Sr-90中选择性去除Y-90的用途

摘要

A method for selectively removing yttrium-90 from its parent strontium- 90 contained in an environmental sample includes loading the sample onto a column containing a chelating ion-exchange resin capable of retaining yttrium-90; washing the column with a solution capable of removing strontium, calcium, and other contaminants from the yttrium-90 fraction retained on the column; removing excess acetate salts from the column; eluting yttrium-90 solution from the column and adjusting the pH of this solution to about 2.7; filtering the yttrium-90 solution and weighing this solution for gravimetric yield; and, counting the yttrium- 90 containing solution with a radiological counter for a time sufficient to achieve the statistical accuracy desired. It is preferred that the chelating ion-exchange resin is a bidente ligand having the chemical name iminodiacetic acid mounted on a divinyl benzene substrate, converted from sodium form to ammonia form.
机译:一种从环境样品中所含的母锶90中选择性除去钇90的方法,该方法包括将样品上样到含有能够保留钇90的螯合离子交换树脂的柱子上。用能够从保留在色谱柱上的钇90馏分中除去锶,钙和其他污染物的溶液洗涤色谱柱;从塔中除去过量的乙酸盐;从柱上洗脱钇90溶液,并将该溶液的pH值调节至约2.7;过滤Yttrium-90溶液并称量该溶液的重量(产率);然后,用放射计数器对含钇90的溶液进行计数,时间应足以达到所需的统计精度。螯合离子交换树脂优选为具有化学名称亚氨基二乙酸的二齿配体,其安装在二乙烯基苯底物上,从钠形式转化为氨形式。

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