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BIAXIALLY STRETCHED POLYPROPYLENE FILM HAVING HIGH SURFACE ELASTIC MODULUS

机译:具有高表面弹性模量的双轴拉伸聚丙烯薄膜

摘要

PROBLEM TO BE SOLVED: To enhance the surface elastic modulus of a biapially stretched polypropylene film by specifying the average isotactic block length of polypropylene molecules, n-heptane insoluble and soluble fractions, a ratio of a wt. average mol.wt. to a number average mol.wt. in mol.wt. distribution, and the surface elastic moduli of a base layer in longitudinal and lateral directions. ;SOLUTION: In polypropylene of a biaxially stretched polypropylene film, the average isotactic block length of polypropylene molecules between two structural carbon chain flaws exceeds 40 on an average and an n-heptane insoluble fraction measured by a 13C-NMR spectral method has a carbon chain isotactic index of at least 95%, a ratio of a wt. average mol.wt. Mw to a number average mol.wt. Mn in mol.wt. distribution is below 4 and an n-heptane soluble fraction is below 1%. The elastic modulus of a base layer is made larger than 2400N/mm2 in the longitudinal direction of the base layer and 4800N/mm2 in the lateral direction thereof and the film may be composed of a multilayer or a single layer.;COPYRIGHT: (C)1997,JPO
机译:解决的问题:通过规定聚丙烯分子的平均全同立构嵌段长度,正庚烷不溶和可溶部分,以重量比计的比率来提高双api拉伸聚丙烯膜的表面弹性模量。平均分子量至数均分子量。以mol.wt.分布,以及基层在纵向和横向的表面弹性模量。 ;解决方案:在双轴拉伸聚丙烯薄膜的聚丙烯中,两个结构碳链缺陷之间的聚丙烯分子的平均等规嵌段长度平均超过40,并且通过 13 C测量的正庚烷不溶级分-NMR光谱法的碳链全同立构指数为至少95%,重量比为100。平均分子量Mw为数均分子量。 Mn(以mol.wt.计)分布低于4,正庚烷可溶级分低于1%。使基底层的弹性模量在基底层的纵向上大于2400N / mm 2 ,在其横向和膜上大于4800N / mm 2 可以由多层或单层组成。;版权所有:(C)1997,日本特许厅

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