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Polysiloxane of the inter-penetrator root network structure - and poly acrylic polymer material, and its production method, the moldings

机译:互穿性根网结构的聚硅氧烷和聚丙烯酸聚合物材料及其生产方法,成型品

摘要

The polysiloxane network (1) of said polymer material is formed by (1a) at least one alpha , omega -dihydroxylated polydimethylsiloxane and/or one alpha , omega -dihydroxylated poly(dimethyldiphenyl)siloxane having at least 70 % of dimethylsiloxane patterns; (1b) a crosslinking agent and/or a bridging agent providing for the crosslinking as well as a link between the networks; optionally (1c) a polycondensation catalyst. The acrylic network (2) is formed by (2a) at least one (meth)acrylic monomer without hydrophylic functional group; optionally (2b) a crosslinking agent and (2c) a radical polymerization initiator. The polymerization mixture contains all these constituents, and a sufficient quantity of a free radical-forming inhibitor to initially prevent the initiator (2c) to produce radicals which, combined with the catalyst (1c), would anihilate the catalytic properties of the catalyst, to form the network (1) before the network (2). Application: fabrication of articles of all shapes.
机译:所述聚合物材料的聚硅氧烷网络(1)由(1a)至少一种具有至少70%的二甲基硅氧烷图案的α,ω-二羟基化的聚二甲基硅氧烷和/或一种α,ω-二羟基化的聚(二甲基二苯基)硅氧烷形成; (1b)提供交联以及网络之间的连接的交联剂和/或桥联剂;任选地(1c)缩聚催化剂。丙烯酸网络(2)由(2a)至少一种不具有亲水性官能团的(甲基)丙烯酸单体形成。任选地(2b)交联剂和(2c)自由基聚合引发剂。聚合混合物包含所有这些成分,以及足以防止引发剂(2c)产生自由基的足够量的自由基形成抑制剂,该自由基与催化剂(1c)结合后,会消灭催化剂的催化性能,从而在网络(2)之前形成网络(1)。应用:制造各种形状的物品。

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