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Reagent for aryl-c-glycosylation and process for preparing aryl-c-glycosyl compounds

机译:芳基-c-糖基化试剂和制备芳基-c-糖基化合物的方法

摘要

Problem: to provide a novel reagent for aryl-C-glycosylation attaining a high yield and exhibiting an excellent selectivity toward beta -configuration and a novel process for preparing aryl-C-glycosyl compounds characterized by using the reagent. Means for solving the problem: a reagent for aryl-C-glycosylation comprising at least one Lewis acid and at least one member selected from among salts of trifluoromethanesulfonic acid and trifluoroacetic acid with silver and mercury; and a process for preparing aryl-C-glycosyl compounds with the reagent.
机译:问题:提供一种新颖的用于芳基-C-糖基化的试剂,其获得高产率并且显示出对β-构型的优异选择性,以及提供一种用于制备芳基-C-糖基化合物的新方法,其特征在于使用该试剂。解决该问题的手段:芳基-C-糖基化试剂,其包含至少一种路易斯酸和选自三氟甲磺酸和三氟乙酸与银和汞的盐中的至少一种。以及用该试剂制备芳基-C-糖基化合物的方法。

著录项

  • 公开/公告号AU6889596A

    专利类型

  • 公开/公告日1997-04-09

    原文格式PDF

  • 申请/专利权人 SANKYO COMPANY LIMITED;

    申请/专利号AU19960068895

  • 申请日1996-09-05

  • 分类号C07D307/20;C07D309/10;B01J31/30;C07B61/00;

  • 国家 AU

  • 入库时间 2022-08-22 03:22:29

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