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REAGENT FOR ARYL-C-GLYCOSYLATION AND PROCESS FOR PREPARING ARYL-C-GLYCOSYL COMPOUNDS

机译:芳基-C-糖基化试剂和制备芳基-C-糖基化合物的方法

摘要

Problem: to provide a novel reagent for aryl-C-glycosylation attaining a high yield and exhibiting an excellent selectivity toward β-configuration and a novel process for preparing aryl-C-glycosyl compounds characterized by using the reagent. Means for solving the problem: a reagent for aryl-C-glycosylation comprising at least one Lewis acid and at least one member selected from among salts of trifluoromethanesulfonic acid and trifluoroacetic acid with silver and mercury; and a process for preparing aryl-C-glycosyl compounds with the reagent.
机译:问题:提供一种高收率且对β-构型具有优异选择性的用于芳基-C-糖基化的新型试剂,以及以该试剂为特征的制备芳基-C-糖基化合物的新方法。解决该问题的手段:芳基-C-糖基化试剂,其包含至少一种路易斯酸和选自三氟甲磺酸和三氟乙酸与银和汞的盐中的至少一种。以及用该试剂制备芳基-C-糖基化合物的方法。

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