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Polymers having an improved heat resistance comprising times imide derivative units

机译:具有改善的耐热性的聚合物,包含两倍的酰亚胺衍生物单元

摘要

The invention relates to a process for the anionic polymerization of a maleimide n - substituted in a solvent, and in the presence of at least one organometallic initiator of alkali metal, which is used as initiator, the dry - butyllithium, sodium alcoholates, diphenylmethyl potassium, or naphthalene lithium or sodium; a process for the preparation of polymer containing maleimide n - substituted with narrow distribution of the molecular masses by anionic polymerization of the maleimide in a solvent, and in the presence of an initiator system formed of at least one organometallic initiator of the alkali metal and of at least one mineral salt and / or an organic salt of an alkali metal or alkaline-earth - earth; a polymer based on a maleimide n - substituted with a mean molecular weight of 12 000 - 100 000; a polymer based on a maleimide n - substituted with a polydispersity 1,1 - 1,5; and a polyblock copolymer in which at least one polymer containing maleimide n - substituted is associated with at least one polymer of monomer (meth) acryligue.
机译:本发明涉及一种在溶剂中被n-取代的马来酰亚胺进行阴离子聚合的方法,并且在至少一种碱金属有机金属引发剂(用作引发剂)的存在下,干丁基锂,醇钠,二苯甲基钾或萘锂或钠;一种通过在溶剂中通过马来酰亚胺的阴离子聚合和在由至少一种碱金属的有机金属引发剂形成的引发剂体系的存在下制备包含分子量分布窄的n-取代的马来酰亚胺的聚合物的方法。至少一种碱金属或碱土金属的矿物盐和/或有机盐;基于马来酰亚胺n-的聚合物,平均分子量为12 000-100 000;基于马来酰亚胺n-的聚合物,该聚合物被多分散性1.1-1.5取代;以及一种多嵌段共聚物,其中至少一种含有被n-取代的马来酰亚胺的聚合物与至少一种单体(甲基)丙烯酸酯的聚合物缔合。

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