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Modified Y-zeolite, process for the preparation thereof, and modified Y- zeolite-containing FCC catalyst

机译:改性的Y-沸石,其制备方法和改性的含Y-沸石的FCC催化剂

摘要

A process for preparing a modified Y-zeolite, in which a NaY- zeolite is first subjected to an ammonium exchange, the resulting ammonium- exchanged zeolite is subjected to an aluminum exchange, the aluminum- exchanged zeolite is subjected to a steam calcination, and a phosphorus component is incorporated into the steam calcined zeolite, is disclosed. The modified Y-zeolite obtained by this process and an FCC catalyst containing the modified Y-zeolite are also disclosed. The FCC catalyst containing the aluminum-exchanged phosphorus-containing Y- zeolite prepared according to the present invention shows less coke make, and an improved selectivity to C.sub.3 olefins compared to FCC catalysts containing zeolites which have either been aluminum exchanged or contain phosphorus.
机译:一种制备改性Y型沸石的方法,其中首先将NaY型沸石进行铵交换,然后将所得的铵交换型沸石进行铝交换,将铝交换型沸石进行蒸汽煅烧,并且公开了一种将磷组分掺入蒸汽煅烧的沸石中。还公开了通过该方法获得的改性Y沸石和包含该改性Y沸石的FCC催化剂。与含有已被铝交换或含有铝的沸石的FCC催化剂相比,根据本发明制备的含有铝交换的含磷的Y-沸石的FCC催化剂显示较少的焦炭生成,并且对C.3烯烃的选择性提高。磷。

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