Large annular conjugate type high polymer and large annular conjugate type high-molecular constituent

摘要

PURPOSE: To obtain a macrocyclic conjugated polymer having improved electric conductivity and stability by reacting tetracyanoethylene with 1,2- diaminotetramethyldisilane. ;CONSTITUTION: Tetracyanoethylene and 1,2-diaminotetramethyldisilane are reacted to give a macrocyclic conjugated polymer. The polymer has a main chain having conjugated cyclic structures each having at least 7 atoms and represented by the formula [wherein X and Y are each a group selected from the group consisting of an unsatd. C-C bond, an unsatd. C-N bond, an unsatd. N-N bond, an arom. ring, a hetrocyclic ring, and their deriv.; and α, β, γ, and δare each H, 1-5C alkyl, NH₂, or NR₂ (wherein R is 1-5C alkyl) provided a may form =NH or =NR with β, and 7 may form NH or NR with δ]. Adjacent cyclic structures of the polymer possess a conjugated group jointly or are linked through a conjugated linkage.;COPYRIGHT: (C)1994,JPO&Japio