首页> 外国专利> Optical recording reclaiming process null of the optical recording media which uses jiarirueten based chemical compound and this jiarirueten based

Optical recording reclaiming process null of the optical recording media which uses jiarirueten based chemical compound and this jiarirueten based

机译:使用基于jaarirueten的化合物和该jiarirueten的光记录介质的光记录回收方法无效

摘要

PURPOSE: To provide a new compound having a photochromic property excellent in thermal stability, repetition durability, semiconductor laser susceptibility and sensitivity, etc., of its colored state and suitable for an optical recording material, etc. ;CONSTITUTION: A compound having a structure of formula I (n is an integer of 2 to 5; l and m are each an integer of 0, l or 2; R1 and R3 are each an alkyl; R2 and R4 are each H, an alkyl, a dialkylamino, cyano, nitro or an alkoxy; A and B are each an aromatic or a heterocycle), e.g. 1,2-bis[5-(4- methoxyphenyl)-2,4-dimethyl-3-thienyl]-3,3,4,4,5,5-hexafluorocyclopentene of formula II. This compound can be obtained, e.g. by synthesizing 3-iodo-5(4- methoxyphenyl)-2,4-dimethylthiophene of formula III from p-iodoanisole, etc., as the raw materials, adding tetrahydrofuran (THF) thereto, cooling it, subsequently adding an n-butyllithiumhexane solution dropwise thereto, then adding a THF solution of perfluorocyclopentene dropwise thereto, subsequently adding water and extracting it with ethyl acetate.;COPYRIGHT: (C)1995,JPO
机译:用途:提供一种具有光致变色性能的新型化合物,该化合物具有良好的热稳定性,重复耐久性,半导体激光敏感性和敏感性等,且具有着色状态,适用于光学记录材料等。组成:具有结构的化合物式I(n是2到5的整数; l 和m分别是0,l或2的整数; R 1 和R 3 < / Sup>分别为烷基; R 2 和R 4 分别为H,烷基,二烷基氨基,氰基,硝基或烷氧基; A和B分别为芳香族或杂环),例如式II的1,2-双[5-(4-甲氧基苯基)-2,4-二甲基-3-噻吩基] -3,3,4,4,5,5-六氟环戊烯。该化合物可以例如通过以下方法获得。通过从对碘苯甲醚等合成式III的3-碘-5(4-甲氧基苯基)-2,4-二甲基噻吩作为原料,向其中添加四氢呋喃(THF),冷却,随后添加正丁基锂己烷向其中滴加全氟环戊烯的四氢呋喃溶液,然后向其中滴加全氟环戊烯的四氢呋喃溶液,随后加水并用乙酸乙酯萃取。;版权所有:(C)1995,日本特许厅

著录项

  • 公开/公告号JP2676698B2

    专利类型

  • 公开/公告日1997-11-17

    原文格式PDF

  • 申请/专利权人 鐘紡株式会社;

    申请/专利号JP19930338827

  • 申请日1993-12-01

  • 分类号C07D333/36;C07D333/12;C07D333/16;C07D333/18;C07D333/24;C07D333/32;C07D333/38;C07D333/42;C07D409/06;C07D417/06;C07D495/04;C09K9/02;G03C5/56;G11B7/00;G11B7/24;

  • 国家 JP

  • 入库时间 2022-08-22 03:00:17

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