NEW MATERIAL:A fluorine-contatning diarylethene derivative expressed by formula I (A and B are formula II or formula III; R1 and R4 are H or alkyl; R2 and R3 are H, alkyl or cyano; n is 2-5). EXAMPLE:1,2-Bis(1,5-dimethyl-2-cyano-4-pyrrolyl)-3,3,4,4,5,5-hexafluor ocyclopentene. USE:Useful for optical recording material, because the derivative expressed by formula I has photochromic property. The derivative expressed by formula I is colored and decolored in a short time and has good repeated endurance. The derivative expressed by formula I can provide new functional property to light-conditioning material such as sun glass or window, clothing or cosmetic. PREPARATION:For example, perfluorocycloalkene expressed by formula IV (n is 2-5) is reacted with 3-pyrrolyl or 3-indolyllithium derivative to provide the compound expressed by formula I.
展开▼
机译:新材料:由式I表示的含氟二芳基乙烯衍生物(A和B为式II或式III; R 1和R 4为H或烷基; R 2和R 3为H,烷基或氰基; n为2-5)。实施例:1,2-双(1,5-二甲基-2-氰基-4-吡咯基)-3,3,4,4,5,5-六氟环戊烯。用途:用于光学记录材料,因为式I表示的衍生物具有光致变色特性。式I表示的衍生物在短时间内被着色和脱色,并且具有良好的重复耐久性。由式I表示的衍生物可以为诸如玻璃或窗户,衣服或化妆品的调光材料提供新的功能特性。制备:例如,将式IV表示的全氟环烯烃(n为2-5)与3-吡咯基或3-吲哚基锂衍生物反应,得到式I表示的化合物。
展开▼