NEW MATERIAL:The compound of formula I having the following physical and chemical properties. Molecular formula, C19H26O4: molecular weight, 318; appearance, white powder; melting point, 257-258 deg.C; solubility, soluble in ethanol, methanol, ethyl acetate and chloroform and insoluble in water and hexane; etc. USE:A carcinostatic agent and a remedy for abnormality of hormone. PREPARATION:The objective compound is produced by dissolving 6beta,14alpha -dihydroxy-4-androstene-3,17-dione of formula II in an organic chloride solvent such as chloroform, passing nitrogen through the solution, sealing with a plug and irradiating with visible light (e.g. solar light, white fluorescent lamp or tungsten lamp) for 4-24hr at normal temperature.
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机译:新材料:具有以下物理和化学性质的式I化合物。分子式,C 19 H 26 O 4:分子量为318;外观,白色粉末;熔点257-258℃。溶解性,易溶于乙醇,甲醇,乙酸乙酯和氯仿,不溶于水和己烷。用途:抗癌剂和激素异常的药物。制备方法:通过将式II的6beta,14alpha -dihydroxy-4-androstene-3,17-dione溶解在有机氯化物溶剂(如氯仿)中,使氮气通过溶液,用塞子密封并用可见光照射,可制得目标化合物常温下(例如太阳能灯,白色荧光灯或钨丝灯)照明4-24小时。
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