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Process for extracting Boron from Brine of natural or industrial using solvent extraction

机译:使用溶剂萃取从天然或工业卤水中萃取硼的方法

摘要

Process for extracting Boron content in natural Brine or industrial, which may also contain Lithium, sodium, calcium, Magnesium, potassium, Chlorine, sulphates and Nitrates,Among other elements and components.The process comprises, basically, the first stage of acidulation of LASALMUERA at a pH of between 0.1 to 6.0, at a Dilution of 1 part in 10 Brine WaterUsing an Acid such as Sulphuric Acid or any other oclorhu00eddrico.A Second Stage extraction, which contact the acidified Brine in one or more stages of empleandocomo extractant, solvent extraction,At least one diol with 6 to 20 carbons in its structure, alone or in combination with a higher aliphatic Alcohol and, Optionally, with unmodificador phasesThis extractant or combination of them dissolved in an organic Solvent of aromatic Solvent in a reason extractanteorgu00e1nico between 1 / 10 and 1 / 1 and a reason to buy organic / aqueousDida between 1 / 10 to 10 / 1, and the contact time between 1 to 60 minutes.Temperature between 0 and 80 degrees centigrade; obtaining a Brine substantially free of an organic loaded with Boron and Boron.A third stage of re Extraction and stripping, contacting the Organic Boron loaded with an Alkaline solution with a pH between 7 and 14,Using a professional Reason acuosoentre / 1 / 10 and 1 / 10 with a contact time in each stage of re extraction from 1 to 60 minutes, at a temperature between 0 and 80 degrees centigrade.Alternatively, the process can include washing steps with an aqueous solution of organic acid to remove other impurities, such as gels, precipitates or CRATE.
机译:提取天然盐水或工业中硼的方法,其中还可能包含锂,钠,钙,镁,钾,氯,硫酸盐和硝酸盐以及其他元素和成分。该方法基本上包括LASALMUERA酸化的第一阶段在0.1到6.0的pH值之间,在10份盐水中稀释1份,使用硫酸或任何其他ocdroheddrico之类的酸第二阶段萃取,该萃取过程是在一个或多个empleandocomo萃取剂阶段与酸化的盐水接触,溶剂萃取,至少一种结构上具有6至20个碳原子的二醇,单独或与高级脂肪族醇结合使用,以及任选地具有非修饰剂相。此萃取剂或它们的组合溶解于芳香族溶剂的有机溶剂中,原因是萃取 u00e1nico在1 / 10和1 / 1之间,以及购买有机 /水性Dida的原因在1 / 10到10 / 1之间,并且接触时间在1到60分钟之间。 0至80摄氏度之间;获得基本不含硼和硼的有机物的卤水。第三阶段的再萃取和汽提,使有机硼与pH为7至14的碱性溶液接触,使用专业的Cucusoenter / 1 / 10和1 / 10,在0至80摄氏度之间的温度下,每个萃取阶段的接触时间为1至60分钟。或者,该方法可以包括用有机酸水溶液洗涤的步骤,以除去其他杂质,例如凝胶,沉淀物或板条箱。

著录项

  • 公开/公告号AR001916A1

    专利类型

  • 公开/公告日1997-12-10

    原文格式PDF

  • 申请/专利权人 SOCIEDAD MINERA SALAR DE ATACAMA S.A.;

    申请/专利号AR19960336480

  • 发明设计人 WILKOMIRSKY FUICA IGOR;

    申请日1996-05-10

  • 分类号B01D11/04;C01B35/02;

  • 国家 AR

  • 入库时间 2022-08-22 02:58:51

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