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Catalyst-free aliphatic thermoplastic polyurethanes

机译:无催化剂的脂肪族热塑性聚氨酯

摘要

The present invention relates to pure polyurethanes containing aliphatic and/or cycloaliphatic diisocyanates, macrodiols having a molecular weight of from 500 to 10,000 and chain extenders having a molecular weight of from 62 to 400, obtainable by reacting aliphatic and/or cycloaliphatic diisocyanates with a macrodiol to give an NCO-containing preadduct, where from 1.5 to 22 mol of diisocyanate are employed per mole of macrodiol, and the chain extension of the preadduct is carried out by means of low-molecular-weight aliphatic and/or cycloaliphatic diols, optionally further diisocyanate - with retention of the abovementioned NCO/OH ratio - is added as chain extender, where the preadduct formation is carried out at 90-150@C and the chain extension is carried out at temperatures of 120-230@C, with the proviso that said reaction conditions are maintained at least until a melt viscosity of at least 2,500 mPas, measured at 120@C, has been reached, and the polyaddition is subsequently continued to completion at any desired time, if necessary at elevated temperatures of up to 240@C. The polyurethanes are preferably used in medical technology.
机译:本发明涉及含有脂肪族和/或脂环族二异氰酸酯,分子量为500-10,000的大分子二醇和分子量为62-400的扩链剂的纯聚氨酯,它们可以通过使脂肪族和/或环脂族的二异氰酸酯与大分子二醇反应而制得。产生含NCO的预加合物,其中每摩尔大分子二醇使用1.5至22摩尔的二异氰酸酯,并且借助于低分子量脂族和/或脂环族二醇进行该预加合物的扩链。加入二异氰酸酯(保持上述NCO / OH比)作为扩链剂,其中预加合物的形成在90-150°C下进行,而扩链在120-230°C下进行,但要注意的是,保持所述反应条件至少直到在120℃下测得的熔融粘度达到至少2,500mPas,并且随后继续加聚需要在任何需要的时间完成,必要时可在高达240°C的高温下使用。聚氨酯优选用于医疗技术。

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