首页> 外国专利> PROCESS FOR THE PREPARATION OF ENOL-LACTONE OF ACETIC 2-OXOCYCLOHEXYLIDENE ACID AND APPLICATION TO THE PREPARATION OF 2-COUMARANONE

PROCESS FOR THE PREPARATION OF ENOL-LACTONE OF ACETIC 2-OXOCYCLOHEXYLIDENE ACID AND APPLICATION TO THE PREPARATION OF 2-COUMARANONE

机译:乙酸2-氧代环己烯基烯醇内酯的制备方法及其在2-香豆烷酮制备中的应用

摘要

A process for the preparation of the enol lactone of 2-oxocyclohexylideneacetic acid in which: 1) the glyoxylic acid is reacted with cyclohexanone in the presence of a halogenated acid in order to to obtain a crude reaction B1, then BR/ 2) is reacted that reaction crude B1 after solubilization in an organic solvent in the presence of a strong acid soluble in said organic solvent or strongly acidic resins in order to to obtain the enol-lactone of 2-oxocyclohexylideneacetic acid which is isolated if desired, BR/ and application to the preparation of 2-coumaranone. / P
机译:一种制备2-氧代环己基次乙酸的烯醇内酯的方法,其中:1)使乙醛酸与环己酮在卤代酸存在下反应,以获得粗反应B1,然后
2)使该反应粗产物B1在有机溶剂中溶解,然后在可溶于所述有机溶剂或强酸性树脂的强酸存在下进行反应,以获得2-氧代环己叉基乙酸的烯醇内酯,如果需要,将其分离,
及其在2-香豆素酮制备中的应用。

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