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Novel compositions of resins (meth) acrylic for marine anti-fouling paints, and the corresponding compositions for paints.

机译:用于船用防污漆的树脂(甲基)丙烯酸的新型组合物,以及用于油漆的相应组合物。

摘要

This composition is soluble in the resin (meth) acrylic is characterized by the fact that it comprises a polymer comprising moieties derived from methacrylic acid esterified by groups - ti (or) 3, as a mixture with the ti (or) 4, which represents the excess of ti (or) 4 having been inserted for the preparation of the polymer in an amount sufficient for the resulting composition is soluble and not in the form of a gel; r representing one from among ethyl, isopropyl, butyl n -, -, 2 -; and t - amyl. It may be the product of esterification in a solvent medium of a polymer comprising moieties derived from methacrylic acid by ti (or) 4, the molar ratio ti / cooh being greater than 1, being preferably between 3 / 1 and 10 / 1; or the product of radical copolymerization in a solvent medium of at least one methacrylic acid esterified by ti (or) 3 and of at least one comonomer in the presence of ti (or) 4, in a quantity which would have matched to a reaction between the methacrylic acid and ti (or) 4 with a molar ratio of 1 / x, x & 1).
机译:该组合物可溶于树脂(甲基)丙烯酸酯中,其特征在于它包含一种聚合物,该聚合物包含由甲基丙烯酸酯化的部分,该甲基丙烯酸酯被基团-ti(or)3酯化,与ti(or)4混合物。为制备聚合物已插入的过量ti(或)4足以使所得组合物可溶而不是凝胶形式; r表示乙基,异丙基,丁基n-,-,2-中的一个;和叔戊基。它可以是在溶剂介质中由ti(或)4组成的包含由甲基丙烯酸衍生的部分的聚合物的酯化产物,ti / cooh的摩尔比大于1,优选在3/1至10/1之间;或至少一种在ti(或)4存在下在溶剂介质中自由基共聚的产物,至少一种被ti(or)3酯化的甲基丙烯酸与至少一种共聚单体在反应介质中的反应<甲基丙烯酸与ti(或)4的摩尔比为1 / x,x> 1)。

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