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Method of producing composite metal hydroxide, composite metal hydroxide obtained thereby and a flame retardant composition obtained thereby and therewith

机译:制备复合金属氢氧化物的方法,由此获得的复合金属氢氧化物以及由此获得的阻燃剂组合物

摘要

A composite metal hydroxide is produced by reacting magnesium- containing aqueous solution (X) including water soluble zinc compound wherein magnesium ion concentration is 0.01 to 1 mol/liter with alkaline material (Y) at a specific reaction equivalent ratio. Further, a composite metal hydroxide represented by the following general formula (1) is produced by hydrothermally treating thus obtained composite metal hydroxide within a temperature range of 100° to 200° C. for aging in chlorine-containing aqueous solution having a specific chlorine ion concentration:PPMg.sub.1-x Zn.sub.x (OH).sub.2 (1) PPwherein x indicates a positive number within a range of 0. 003≦x≦0.1. A uniform metallic solid solution can be obtained as a composite metal hydroxide by the above series of processes. Further, its crystal shape can be controlled thereby so as to restrain occurrence of secondary aggregation. Still further, a flame retardant high-molecular composition obtained by including thus obtained composite metal hydroxide into a high-molecular weight composition exerts high flame retardancy and shows superiority in mechanical strength.
机译:通过使包含镁离子浓度为0.01〜1 mol / L的水溶性锌化合物的含镁水溶液(X)与碱性物质(Y)以特定的反应当量比反应,来制造复合金属氢氧化物。此外,通过在100℃至200℃的温度范围内对如此获得的复合金属氢氧化物进行水热处理以在具有特定氯离子的含氯水溶液中进行老化,从而制备由以下通式(1)表示的复合金属氢氧化物浓度:

P> Mg 1-x Zn x(OH)2(1)P> P,其中x表示在0范围内的正数。 x≦ 0.1。通过上述一系列方法,可以获得作为复合金属氢氧化物的均匀的金属固溶体。此外,由此可以控制其晶体形状以抑制二次聚集的发生。另外,通过将这样获得的复合金属氢氧化物包含在高分子量组合物中而获得的阻燃性高分子组合物发挥高阻燃性,并且机械强度优异。

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