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The hydrocracking paraffins end of the fischer - tropsch with the aid of catalysts based on zeolite y (h) -.
The hydrocracking paraffins end of the fischer - tropsch with the aid of catalysts based on zeolite y (h) -.
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机译:在基于沸石y(h)-的催化剂的帮助下,费歇尔-tropsch的加氢裂化石蜡末端。
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摘要
Process for hydrocracking of feedstocks originating from the Fischer-Tropsch process, in which a) hydrogen is reacted with the feedstock in contact with a catalyst 1 in a first reaction zone, the said catalyst 1 comprising at least one alumina-based matrix and at least one component for hydrodehydrogenation, b) the effluent originating from the first reaction zone is brought into contact with a catalyst 2 in a second reaction zone, the said catalyst 2 comprising - from 20 to 97 % by weight of at least one matrix - from 3 to 80 % by weight of at least one zeolite Y in hydrogen form, the said zeolite being characterised by an SiO2/Al2O3 molar ratio higher than 4.5, a sodium content lower than 1 % by weight, determined on zeolite calcined at 1100 DEG C, an elementary crystal lattice constant a0 lower than 24.70 x 10-10 m, and a specific surface, determined by the BET method, greater than 400 m2.g-1, - at least one component for hydrodehydrogenation.
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机译:源自费-托工艺的原料的加氢裂化方法,其中a)使氢与在第一反应区中与催化剂1接触的原料反应,所述催化剂1包含至少一种氧化铝基基质和至少一个用于加氢脱氢的组分,b)使来自第一反应区的流出物在第二反应区中与催化剂2接触,所述催化剂2包含-按重量计从20%至97%的至少一种基质-从3% -80重量%的至少一种氢形式的沸石Y,所述沸石的特征在于SiO 2 / Al 2 O 3摩尔比高于4.5,钠含量低于1重量%,基于在1100℃下煅烧的沸石测定, -至少24.70×10 -10 m的基本晶格常数a 0和通过BET法测定的比表面大于400 m 2 .g -1-至少一种加氢脱氢组分。 <
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