首页> 外国专利> PROCESS FOR PRODUCING CELLULOSE DERIVATIVES WHERE AMMONIA ACTIVATED CELLULOSE IS IMPREGNATED WITH ALKALI SOLUTION AND THEN SUBJECTED TO EITHER A SUBSTITUTION OR ADDITION REACTION

PROCESS FOR PRODUCING CELLULOSE DERIVATIVES WHERE AMMONIA ACTIVATED CELLULOSE IS IMPREGNATED WITH ALKALI SOLUTION AND THEN SUBJECTED TO EITHER A SUBSTITUTION OR ADDITION REACTION

机译:氨活化纤维素浸渍有碱溶液,然后再进行取代或加成反应的纤维素衍生物的制备方法

摘要

Disclosed is a method for producing cellulose derivatives wherein cellulose is impregnated with an alkali solution, the impregnated cellulose is selectably pressed out, and the cellulose undergoes a substitution or addition reaction, whereby the cellulose derivative is obtained with a degree of substitution DS. The applied cellulose is an ammonia activated cellulose. The molar ratio of the alkali to the AHG (anhydro glucose unit) in the cellulose at the beginning of the substitution or addition reaction does not exceed twice the valve of the desired DS. For the swelling of cellulose, no excess of alkali is required, which does not react to produce alkali cellulose but only adheres to the cellulose as a loose association product. Reagent consumption in the substitution or addition reaction is lower. Fewer secondary products are formed.
机译:公开了一种纤维素衍生物的制造方法,其中,将纤维素用碱溶液浸渍,将浸渍的纤维素选择性地压出,并使纤维素进行取代或加成反应,从而得到取代度为DS的纤维素衍生物。施加的纤维素是氨活化的纤维素。在取代或加成反应开始时,纤维素中碱与AHG(脱水葡萄糖单元)的摩尔比不超过所需DS阀的两倍。对于纤维素的溶胀,不需要过量的碱,其不会反应生成碱纤维素,而仅作为疏松缔合产物粘附至纤维素。取代或加成反应中的试剂消耗较低。形成的次级产品更少。

著录项

  • 公开/公告号NZ330917A

    专利类型

  • 公开/公告日1999-10-28

    原文格式PDF

  • 申请/专利权人 RHODIA ACETOW AG;

    申请/专利号NZ19970330917

  • 发明设计人 KARSTENS TIES;STEIN ARMIN;

    申请日1997-11-04

  • 分类号C08B1/00;C08B1/02;C08B1/06;C08B1/08;

  • 国家 NZ

  • 入库时间 2022-08-22 02:26:27

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