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Solvents and new electrolytic compositions having a large stability range and high conductivity

机译:具有大稳定性范围和高电导率的溶剂和新型电解质组合物

摘要

The present invention relates to new polar solvents corresponding to the general formula: R 1 F 2 NX (Z) R 7 in which X = C or SO; Z = O, NSO2NR3R4 or NCN; R 1 and R 2 are the same or different and represent C1-18alkyle, C1-18oxaalkyle, C1-18alkylène or C1-18oxaalkylène; R 3 to R 6 are the same or different and represent C1-18alkyle or C1-18oxaalkyle; R 7 is an RF group, an RFCH2O-, (RF) 2CHO-, (RFCH2) 2N- or NR 5 R 6 group; RF is a fluorine atom, a C1-4alkyle, C1-4oxaalkyle or C1-4azaalkyle group, with the restrictions that: 1) if Z = O, then RF is not C1-4alkyle; and 2) if Z = O and X = SO, then RF is not C1-4alkyl or C1-4oxaalkyle and new electrolytic compositions arising therefrom and having a high stability domain, as required for applications in the electrochemical field . These solvents have a very polar amide function, and are preferably combined with a salt soluble in said solvent and having an anion with delocalized charge, and at least one polymer, to form an electrolytic composition.
机译:本发明涉及对应于通式:R 1 F 2 NX(Z)R 7的新的极性溶剂,其中X = C或SO;和Z = O,NSO2NR3R4或NCN; R 1和R 2相同或不同,表示C 1-18烷基,C 1-18氧杂烷基,C 1-18烷基或C 1-18氧杂烷基。 R 3〜R 6相同或不同,表示C1-18烷基或C1-18氧杂烷基。 R <7>是RF基团,是RFCH2O-,(RF)2CHO-,(RFCH2)2N-或NR <5> R 6基团; RF是氟原子,C1-4烷基,C1-4氧杂烷基或C1-4氮杂烷基,其限制条件为:1)如果Z = O,则RF不是C1-4烷基;和2)如果Z = O且X = SO,则RF不是C 1-4烷基或C 1-4氧杂烷基,并且由此产生的且具有高稳定性域的新的电解质组合物,这是电化学领域中所需要的。这些溶剂具有非常极性的酰胺官能,并且优选与可溶于所述溶剂并且具有带离域电荷的阴离子的盐和至少一种聚合物结合,以形成电解质组合物。

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