首页> 外国专利> Treatment Method of Acid Mine Drainage Using SRBSulfate Reducing Bacteria and the Process of AFRMAnaerobic Floating Media Reactor

Treatment Method of Acid Mine Drainage Using SRBSulfate Reducing Bacteria and the Process of AFRMAnaerobic Floating Media Reactor

机译:SRBS硫酸盐还原菌处理酸性矿山废水的方法及AFRM厌氧浮介质反应器工艺

摘要

Acid mine waste water resulting from oxidation of the ground water and the mineral oxide is it contains a low pH, high heavy metal sulfates such as (SO 42-) and the concentration of iron, manganese, zinc, copper at a high concentration close to the acidified water and in water thereby killing the microbial habitat, birds, and fish are. In addition, severe damage to the rock, mine waste, by reaction as the concrete sikimyeo erode the structure, by dissolving the human body and organisms (such plants, microorganisms, etc.) harmful toxic metals (copper, zinc, cadmium, manganese, lead, and so on) the environment so causing the destruction of the ecosystem, there is a need to bring such appropriate measures for this; Thus, the present invention is a variety of heavy metals present in these acid mine drainage sulfate-reducing bacteria; were to be removed by using the (Sulfate Reducing Bacteria than SRB), a conventional method which is different from Shin anaerobic process in the removal of these heavy metals AFMR ( anaerobic floating media reactor; developed an anaerobic reaction vessel floating media) treatment step, this treatment step may belong to the field of waste water in any high level waste water treatment technology is applicable for containing various heavy metals.; Physical and chemical processes have been used to remove heavy metals from the environment, but these conventional methods have the disadvantage that the second generation and heavy metal removal rates and high costs of operation of the low efficiency of the pollutant costs. Accordingly, there is a study of the heavy metal removal technology is going on in various ways around the world, the present invention is an anaerobic treatment step of sulfate-reducing bacteria (SRB) existing in these physical and chemical methods, and is a different biological heavy metal removal technique It can be referred to as heavy metal removal process using.; These sulfates heavy metal removal using a reducing bacteria (SRB) process organic matter to by using as an electron donor sulfide generated when the reduction of the sulphate (Sulfate) to the sulfide (Sulfide) (Sulfide) is reacted with various heavy metals present in the waste water sulphide by forming the precipitation (precipitation Sulfide) utilizes the reaction mechanism of removing the heavy metals in biological. This makes it also suggests the possibility of recovery of heavy metals from waste water, as well as the removal of heavy metals, according to the characteristics of the waste water from the waste water. The heavy metals are removed in the same way sulfide is low there is a risk of re-eluted by changing the carbon dioxide and bicarbonate, the organic carbon source in anaerobic digestion since thereby resulting in increasing the alkalinity of the heavy metals from waste water of the coal and metal mines and contains a large amount of sulfate It was an effective way to remove.; The present invention up filling the Floating Media in-flow anaerobic reactor; stylized (AFMR Anaerobic Floating Media Reactor), and the strain of the In sulfate-reducing bacteria the surface of the Media filled in the anaerobic reactor to form the biofilms (biofilm), thus formed SRB biofilms (biofilm) by using an organic substance as an electron donor sulphate (SO 4=) sulfide (S =) the formed sulphides are present various heavy metals react with the metal sulfide precipitate (metal sulfide Precipitation) which in the acid mine drainage by reduction with to remove the heavy metals by forming.; As was the effect of the present invention, the generation of secondary pollutants small compared to traditional heavy metal treatment method, it is not only possible to obtain a high removal efficiency of heavy metals can be economically reduce the number of operating costs.
机译:地下水和矿物氧化物的氧化产生的酸性矿山废水中含有低pH值,高重金属硫酸盐,例如(SO 4 2-)和高浓度的铁,锰,锌,铜接近酸化水和水中,从而杀死微生物栖息地,鸟类和鱼类。此外,由于混凝土sikimyeo侵蚀结构,溶解人体和生物(例如植物,微生物等)有害有毒金属(铜,锌,镉,锰,铅等)环境,从而导致生态系统遭到破坏,因此需要为此采取适当措施;因此,本发明是存在于这些酸性矿井排水硫酸盐还原菌中的多种重金属;使用硫酸还原菌(比SRB还原菌)去除,这是不同于Shin厌氧工艺的常规方法,去除这些重金属AFMR(厌氧浮动介质反应器;开发了厌氧反应容器浮动介质)处理步骤,该处理步骤可能属于废水领域,任何适用于盛放各种重金属的高级废水处理技术都可以;已经使用物理和化学方法从环境中去除重金属,但是这些常规方法的缺点是第二代和重金属的去除率高以及操作成本高,污染成本低。因此,全世界对重金属去除技术的研究正在以各种方式进行,本发明是存在于这些物理和化学方法中的硫酸盐还原细菌(SRB)的厌氧处理步骤,并且是不同的。生物重金属去除技术可以称为重金属去除工艺。这些硫酸盐通过还原细菌(SRB)处理有机物而去除,通过将硫酸盐(Sulfate)还原为硫化物(Sulfide)(Sulfide)时所产生的各种重金属进行反应而生成的硫化物用作电子供体。通过形成沉淀的废水硫化物(沉淀硫化物)利用了生物中去除重金属的反应机理。这也暗示了根据废水中废水的特性从废水中回收重金属以及去除重金属的可能性。重金属的去除方法与硫化物含量低的方式相同,存在通过改变二氧化碳和碳酸氢盐(厌氧消化中的有机碳源)而重新洗脱的风险,因为这样会增加废水中重金属的碱度煤矿和金属矿中含有大量的硫酸盐,这是一种有效的去除方法。本发明向上填充了浮介质流入流厌氧反应器; (AFMR厌氧浮动培养基反应器),然后将还原硫酸盐细菌的菌株填充到厌氧反应器中的培养基表面,形成生物膜(生物膜),从而通过使用有机物质作为有机物形成SRB生物膜(生物膜)。电子给体硫酸盐(SO 4 =)硫化物(S =)形成的硫化物存在,各种重金属与金属硫化物沉淀反应(金属硫化物沉淀),其通过在酸性矿山排水中通过还原而形成,以除去重金属。由于得到了本发明的效果,与传统的重金属处理方法相比,产生的次级污染物少,因此不仅可以获得高的重金属去除效率,而且可以经济地减少运行成本。

著录项

  • 公开/公告号KR19990068454A

    专利类型

  • 公开/公告日1999-09-06

    原文格式PDF

  • 申请/专利权人 백병천;김광복;송영채;

    申请/专利号KR19990018587

  • 发明设计人 백병천;김광복;송영채;

    申请日1999-05-18

  • 分类号C02F3/34;

  • 国家 KR

  • 入库时间 2022-08-22 02:16:48

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