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CATALYST FOR VAPOR-PHASE EPOXIDATION OF OLEFINS AND METHOD OF PRODUCTION OF CATALYST CARRIER

机译:气相汽相氧化烯烃的催化剂及催化剂载体的生产方法

摘要

FIELD: catalyst for production of ethylene oxide. SUBSTANCE: catalyst for production of ethylene oxide contains silver and one or several promoters from alkali metal applied to carrier whose crushing strength is at least 2-3 kg and definite bulk density of at least 0.48 kg/l, which includes the first and second components of alpha-aluminum oxide. In this case, the first component of alpha-aluminum oxide in the form of particles having average size of crystallites of 0.4-4 mcm amounts from 95 to 40% of total weight of alpha-aluminum oxide in carrier; the second component of alpha-aluminum oxide produced in situ by sol-gel process makes up the remaining amount of alpha-aluminum oxide in carrier. Titanium oxide is optionally added to carrier. The invention also covers description of the method of producing carrier of the catalyst. Catalyst have unique carrier from aluminum oxide . EFFECT: improved selectivity and/or activity. 17 cl, 6 tbl
机译:领域:用于生产环氧乙烷的催化剂。物质:用于生产环氧乙烷的催化剂包含银和一种或几种来自碱金属的助催化剂,该助催化剂施加到载体上,其抗压强度至少为2-3 kg,确定的堆积密度至少为0.48 kg / l,包括第一和第二组分的α-氧化铝。在这种情况下,以微晶平均尺寸为0.4-4mcm的颗粒形式的α-氧化铝的第一组分占载体中α-氧化铝总重量的95%至40%。通过溶胶-凝胶法原位生产的α-氧化铝的第二种成分弥补了载体中剩余的α-氧化铝的量。任选地将氧化钛添加到载体中。本发明还涵盖了生产催化剂载体的方法的描述。催化剂具有独特的氧化铝载体。效果:提高了选择性和/或活性。 17厘升,6汤匙

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