首页> 外国专利> PROCESS FOR THE PRODUCTION OF UREA-BASED AMINOPLASTIC AQUEOUS RESINS, FORMOL AND MELANINE, THEIR USE AS GLUES IN THE MANUFACTURE OF MATERIALS DERIVED FROM WOOD, AND THEIR RESULTING WOOD-DERIVED MATERIALS

PROCESS FOR THE PRODUCTION OF UREA-BASED AMINOPLASTIC AQUEOUS RESINS, FORMOL AND MELANINE, THEIR USE AS GLUES IN THE MANUFACTURE OF MATERIALS DERIVED FROM WOOD, AND THEIR RESULTING WOOD-DERIVED MATERIALS

机译:制备尿素基热塑性塑料,甲醛和黑色素的水溶液,将其用作胶粘剂制造木材的材料以及其产生的木材衍生材料的过程

摘要

Such a resin is prepared with a melamine content in the final resin of 10-40% by weight by condensing urea, formalin and melamine, and adding urea to obtain a molar ratio. Final F / NH 2 of 0.25-0.85. (a) Refluxed for up to 15 min. at pH 7-8.5, an aqueous mixture of urea, formaldehyde and melamine at F / NH 2 = 0.85-1.15; (b) the first condensation step is carried out at pH 5-6, 5 and 70.degree.-100.degree. C., to a degree of condensation corresponding to a 25.degree. C. viscosity whose value depends on the active substance, and the condensation is stopped in bringing the pH to 7-8, and the temperature, to 60-80degC; (c) the second condensation step is carried out by adding formalin, urea and the remaining melamine for an F / NH 2 of 0.6-0.9, and is condensed at pH 8-10 and 70-100 degrees C, up to a degree of condensation corresponding to a 25.degree. C. viscosity whose value depends on the active ingredient, and (d) a post-addition of urea is carried out, the NH.sub.2 groups comprising the moles of urea and melamine. . / P
机译:通过缩合尿素,福尔马林和三聚氰胺,并加入尿素以获得摩尔比,制备最终树脂中的三聚氰胺含量为10-40重量%的这种树脂。最终F / NH 2为0.25-0.85。 (a)回流最多15分钟。在pH 7-8.5下,F / NH 2 = 0.85-1.15的尿素,甲醛和三聚氰胺的含水混合物; (b)第一缩合步骤在pH 5-6、5和70.-100°C下进行。 C.,凝结度相当于25.degree。 C.粘度,其值取决于活性物质,并且通过使pH达到7-8和温度达到60-80℃而停止缩合; (c)第二个冷凝步骤是通过添加福尔马林,尿素和剩余的三聚氰胺以实现F / NH 2为0.6-0.9,并在pH 8-10和70-100摄氏度下冷凝至凝结对应于25.degree。 C.粘度,其值取决于活性成分,和(d)进行尿素的后添加,NH 2基团包括尿素和三聚氰胺的摩尔数。 。

著录项

  • 公开/公告号FR2770530A1

    专利类型

  • 公开/公告日1999-05-07

    原文格式PDF

  • 申请/专利权人 ATOFINA;

    申请/专利号FR19970013703

  • 发明设计人 JACK LALO;ROGER GARRIGUE;

    申请日1997-10-31

  • 分类号C08G12/38;B27N3/00;C09J161/28;

  • 国家 FR

  • 入库时间 2022-08-22 02:10:20

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