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Process for producing ceramic matrix composites by liquid infiltration of ceramic polymeric precursors

机译:通过液体渗透陶瓷聚合物前体制备陶瓷基复合材料的方法

摘要

Ceramic matrix composites (CMC) of high density, preferably of the type SiC/SiC, are provided by a production process based on the infiltration of ceramic fiber cloths with a polymeric precursor solution containing, as fillers, inert powders having size much lower than the mean distance among the ceramic fibers which are used as basic material for the manufacturing of CMC, typically a nanometric granulometry. Such step is followed by the steps of hardening the cloths, pyrolysis of the polymer and repeated thickenings until the desired density is reached. A possible alternative process comprises a brief ( 24 hours) treatment of infiltration of SiC from the vapor phase (CVI) with precursors and typical operative parameters for the deposition of silicon carbide followed by the repeated thickenings.
机译:高密度的陶瓷基复合材料(CMC),最好是SiC / SiC类型,是通过一种生产工艺来提供的,该工艺基于陶瓷纤维布的浸渗,其中聚合物前体溶液中的惰性粉末作为填料,该惰性粉末的尺寸远小于用作制造CMC的基本材料的陶瓷纤维之间的平均距离,通常是纳米粒度。该步骤之后是使布料硬化,聚合物热解并重复增稠直至达到所需密度的步骤。可能的替代方法包括使用前体对碳化硅从气相(CVI)渗入的短暂处理(<24小时)和典型的操作参数,以沉积碳化硅,然后进行重复增稠。

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