首页> 外国专利> FORM TAPE CONTAINING PRESSURE SENSITIVE ADHESIVE HAVING IMPROVED ADHESIVE PROPERTY TO ACID RAIN-RESISTANT AUTOMOTIVE PAINT

FORM TAPE CONTAINING PRESSURE SENSITIVE ADHESIVE HAVING IMPROVED ADHESIVE PROPERTY TO ACID RAIN-RESISTANT AUTOMOTIVE PAINT

机译:包含压敏胶的胶纸具有改善的耐酸性汽车涂料的胶粘性能

摘要

PROBLEM TO BE SOLVED: To obtain the subject tape having excellent adhesive properties to acidic surfaces by bringing the tape to contain a core layer, a specific pressure sensitive adhesive and a specific crosslinking agent in specific proportions. SOLUTION: This form tape contains (A) a core layer, =100 pts.wt. of a pressure sensitive adhesive containing a crosslinked copolymer obtained from monomers (i)-(iii), about 60-90 pts.wt. of (i) a monomer comprising a monofunctional unsaturated (meth)acrylate ester of a non-tertiary alkyl (a 4-12C alkyl) alcohol, and having = about -20 deg.C glass transition temperature as a homopolymer thereof, approximately 40-10 pts.wt. of (ii) a basic copolymerizable monomer expressed by formula I [(a) is 0-1; (b) is 1; R is H or CH3; X is O or NH; Y is a divalent bond; Z is a non-sterically hindered group expressed by formula II (R1 and R2 are each alkyl)] and about 0-3 pts.wt. of (iii) an acidic monomer copolymerizable with the monomer (i) and the monomer (ii) and (B) a free radical polymerizable crosslinking agent of about 0.051-1 wt.% based on the sum weight of the monomers (i)-(iii).
机译:要解决的问题:通过使胶带包含芯层,特定的压敏粘合剂和特定的交联剂,来获得对酸性表面具有优异粘合性能的主题胶带。 SOLUTION:该胶带包含(A)芯层,<= 100pts.wt。包含约60-90pts.wt。%的包含由单体(i)-(iii)获得的交联共聚物的压敏粘合剂。 (i)包含约40的单体的单体,该单体包含非叔烷基(4-12C烷基)醇的单官能不饱和(甲基)丙烯酸酯,且其玻璃化转变温度小于或等于-20℃ -10点(ii)由式I表示的碱性可共聚单体[(a)为0-1; (b)为1; R为H或CH 3; X为O或NH; Y是二价键; Z是由式II表示的非空间受阻基团(R 1和R 2各自为烷基)]和约0-3pts.wt。 (iii)可与单体(i)和单体(ii)共聚的酸性单体,以及(B)基于单体(i)的总重量计约0.051-1 wt。%的自由基可聚合的交联剂, (iii)。

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