首页> 外国专利> RESIN COMPOSITIONS FOR FIBER-REINFORCED COMPOSITE MATERIALS AND PROCESSES FOR PRODUCING THE SAME, PREPREGS, FIBER-REINFORCED COMPOSITE MATERIALS, AND HONEYCOMB STRUCTURES

RESIN COMPOSITIONS FOR FIBER-REINFORCED COMPOSITE MATERIALS AND PROCESSES FOR PRODUCING THE SAME, PREPREGS, FIBER-REINFORCED COMPOSITE MATERIALS, AND HONEYCOMB STRUCTURES

机译:纤维增强复合材料的树脂组合物及其制备方法,预浸料,纤维增强复合材料和蜂窝结构

摘要

The present invention provides a prepreg excellent in self adhesiveness to a honeycomb core, low in porosity when used as skin panels, excellent in surface smoothness (low in surface porosity) when used as skin panels, and good in tackiness and drapability, and also provides a honeycomb sandwich panel high in skin panel peel strength and excellent in impact resistance and hot water resistance, and a resin composition for a fiber reinforced composite material to allow the above. The present invention has the following constitution. A resin composition for a fiber reinforced composite material comprising the components ÄAÜ, ÄBÜ and ÄCÜ are essential wherein the modulus of storage rigidity G' measured by parallel plates having vibration frequency of 0.5 Hz during elevation of temperature from 50 DEG C at 1.5 DEG C/min is in a range of 5 to 200 Pa in an entire range of 70 DEG C to 100 DEG C. A resin composition for a fiber reinforced composite material comprising the components ÄAÜ , ÄBÜ and ÄCÜ are essential, wherein the minimum modulus of storage rigidity G'min and the maximum modulus of storage rigidity G'max at 70 DEG C to 100 DEG C measured by parallel plates having vibration frequency of 0.5 Hz during elevation of temperature from 50 DEG C at 1.5 DEG C/min, satisfy the following relation: MATH A resin composition for a fiber reinforced composite material comprising the components ÄAÜ, ÄBÜ and ÄCÜ are essential, wherein the thixotropy index is in a range of 2.5 to 40, the resin viscosity at 80 DEG C measured by parallel plates having vibration frequency of 0.5 Hz during elevation of temperature from 50 DEG C at 1.5 DEG C/min is in a range of 100 to 1000 poises, and the minimum value of resin viscosity during heating is 30 to 400 poises. A resin composition for a fiber reinforced composite material comprising the components ÄAÜ, ÄBÜ and ÄCÜ are essential, wherein solid rubber and fine silica particles are contained as component ÄCÜ by 1 to 10 wt%, respectively, based on the total weight of the resin composition. The fiber reinforced composite material using the prepreg of the present invention can be used widely for airplanes, automobiles and other industrial applications, particularly as structural materials of airplanes, because of its excellent mechanical properties.
机译:本发明提供了一种预浸料坯,其对蜂窝芯的自粘性优异,当用作蒙皮板时孔隙率低,当用作蒙皮板时表面光滑性优异(表面孔隙率低),并且粘性和悬垂性良好。蜂窝状夹心板的蒙皮面板剥离强度高,并且耐冲击性和耐热水性优异,并且用于纤维增强复合材料的树脂组合物满足上述要求。本发明具有以下构成。用于纤维增强复合材料的树脂组合物是必需的,其中包含组分ÄAÜ,ÄBÜ和ÄCÜ,其中在温度从50℃升高到1.5℃时,由振动频率为0.5 Hz的平行板测量的储能刚性模量G'。在70℃至100℃的整个范围内,min的范围为5至200 Pa。用于纤维增强复合材料的树脂组合物是必不可少的,其中包含组分ÄAÜ,ÄBÜ和ÄCÜ,其中最小的储存刚性模量在温度从50℃以1.5℃/ min升高时,通过振动频率为0.5Hz的平行板在70℃至100℃下测量的G'min和最大储存刚性模量G'max满足以下关系:用于纤维增强复合材料的树脂组合物是必不可少的,其中包含组分ÄAÜ,ÄBÜ和ÄCÜ,其中触变性指数为2.5至40,80℃时的树脂粘度在温度从50℃以1.5℃/ min升高的过程中,具有0.5Hz振动频率的平行板的d在100至1000泊的范围内,并且加热期间树脂粘度的最小值为30至400泊。包含组分ÄAÜ,ÄBÜ和ÄCÜ的纤维增强复合材料的树脂组合物是必不可少的,其中固体橡胶和二氧化硅细粒分别占组分ÄCÜ的1至10 wt%,基于树脂组合物的总重量。使用本发明的预浸料的纤维增强复合材料由于其优异的机械性能而可广泛用于飞机,汽车和其他工业应用,特别是作为飞机的结构材料。

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