首页> 外国专利> Substrate surface, useful for the production of easy clean systems, comprises a hydrolyzable compound condensate having a microstructure such that the contact angle with water or oil is increased.

Substrate surface, useful for the production of easy clean systems, comprises a hydrolyzable compound condensate having a microstructure such that the contact angle with water or oil is increased.

机译:可用于生产易于清洁的系统的基材表面包含具有微结构的可水解化合物缩合物,使得与水或油的接触角增加。

摘要

A substrate has a surface comprising a condensate of at least one hydrolyzable compound of a main group III-V element and/or secondary group (II)-(IV) element and has a microstructure such that the contact angle with water or hexadecane is at least 5 deg greater than that of the corresponding smooth surface. A substrate (I) has a microstructured surface comprising: (A) a composition consisting of a condensate of at least one hydrolyzable compound of an element (M) of a main group III-V element and/or secondary group (II)-(IV), whereby at least a portion the compound contains a hydrolyzable group (A2) and a non-hydrolyzable carbon containing group (A2) and the molar ratio of (A) to (A2) in the corresponding monomeric starting compounds is 10:1-1:2. 0.1-100 mol. % of (A2) are (A2') that have on average 5-30 fluorine atoms that are bonded to one or more aliphatic carbon atoms that are separated by at least two (M) atoms; and (B) a microstructure of a type such that the contact angle with water or hexadecane is at least 5 deg greater than that of the corresponding smooth surface. An Independent claim is included for a process for the preparation of (I) by either: (i) embossing the surface of a deposited coating with a die, before or during drying and/or curing, that has a non-polar and/or low energy surface or (ii) incorporating nanoscale inorganic solid particles or agglomerates having a particle size of at least 50 nm.
机译:基材具有包含至少一种III-V族主族和/或(II)-(IV)主族的可水解化合物的缩合物的表面,并且其微观结构使得与水或十六烷的接触角为至少比相应的光滑表面大5度。基材(I)具有微结构化表面,该表面包含:(A)由至少一种主要的III-V族元素和/或次要的(II)-元素(M)的可水解化合物的缩合物组成的组合物IV),其中所述化合物的至少一部分包含可水解基团(A2)和不可水解含碳基团(A2),并且相应的单体起始化合物中的(A)与(A2)的摩尔比为10:1 -1:2。 0.1-100摩尔(A2)的%是(A2′),其平均具有5-30个氟原子,所述氟原子键合至被至少两个(M)原子隔开的一个或多个脂族碳原子上; (B)一种微结构,其与水或十六烷的接触角至少比相应的光滑表面大5度。对于制备(I)的方法包括独立权利要求,该方法是:(i)在干燥和/或固化之前或期间,用模具对沉积涂层的表面进行模压,该表面具有非极性和/或低能表面或(ii)掺入粒径至少为50 nm的纳米级无机固体颗粒或团聚物。

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