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Modified, fine-particle, water-insoluble aziridine polymer and use therefore for removing heavy metals from aqueous solution

机译:改性的细颗粒,水不溶性氮丙啶聚合物,因此可用于从水溶液中去除重金属

摘要

Process for preparing fine-particle, water-insoluble polymers of aziridines by polymerizing aziridines, preferably ethylenimine, in the presence of crosslinkers which contain at least two functional groups, and in at least one ether, and also modified, water-insoluble polymers of aziridines which can be obtained by reacting fine-particle, water- insoluble, crosslinked polymers of aziridines, in aqueous medium, with carbon disulfide or formaldehyde and a nucleophilic agent from the group consisting of alkali metal cyanides, primary amines, secondary amines, alkali metal sulfites and alkali metal phosphites, and use of the modified and non-modified fine-particle, water-insoluble polymers for immobilizing active compounds, as absorbents for aldehydes, ketones and acids, and also for removing heavy metal ions from wastewaters.
机译:在具有至少两个官能团的交联剂的存在下,在至少一种醚中,通过聚合氮丙啶,优选亚乙基亚胺,制备氮丙啶的细粒,水不溶性聚合物的方法,以及改性的氮丙啶的水不溶性聚合物可以通过在水介质中使氮丙啶的细颗粒,水不溶性交联聚合物与二硫化碳或甲醛和亲核试剂反应而获得,该碱金属氰化物,伯胺,仲胺,碱金属亚硫酸盐和碱金属亚磷酸盐,以及改性和非改性的水不溶性细颗粒聚合物用于固定活性化合物,醛,酮和酸的吸收剂以及从废水中去除重金属离子的用途。

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