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Light-and bright-colored antifouling paints

机译:浅色和彩色防污漆

摘要

2-trihalogenomethyl-3-halogeno-4-cyano pyrrole derivatives which are substituted in position 5 and optionally in position 1 are used as barnaclecide in antifouling paints, which can therefore be formulated as light- or bright-colored, particularly as bright white. The halogens in positions 2 and 3 are independently selected from the group consisting of florine, chlorine and bromine, preferably florine in position 2 and bromine in position 3. The substituent in position 5 is selected from the group consisting of C1-8 alkyl, C1-8 monohalogenoalkyl, C5-6 cycloalkyl, C5-6 monohalogenocycloalkyl, benzyl, phenyl, mono- and di- halogeno- benzyl or -phenyl, mono- and di-C1-4 alkyl benzyl or phenyl, and monohalogeno mono-C1-4-alkyl benzyl or phenyl, the halogen being selected from the group consisting of chlorine and bromine, prefereably chlorine; the most preferred substituent in position 5 is parachlorophenyl. The optional substituent in position 1 is selected from the group consisting of C1-4 alkyl and C1-4 alkoxy C1-4 alkyl; it is preferred that no substituent be present in position 1. The most preferred compound for use as barnaclecide in the invention is 2- trifluoromethyl-3-bromo-4-cyano-5- parachlorophenyl pyrrole. Antifouling paints may contain 0.5 to 9.9 wt % of barnaclecide, based on the total weight of the dry mass of the composition, preferably 1 to 6 wt %, most preferably 1.5 to 4 wt %.
机译:在位置5和任选地位置1被取代的2-三卤代甲基-3-卤代-4-氰基吡咯衍生物用作防污漆中的藤壶,因此可以配制成浅色或亮色,特别是亮白色。 2和3位的卤素独立地选自:植物,氯和溴,优选2位的植物和3位的溴。5位的取代基选自C 1-8烷基,C 1。 -8一卤代烷基,C5-6环烷基,C5-6一卤代环烷基,苄基,苯基,单和二卤代苄基或-苯基,一和二-C1-4烷基苄基或苯基以及一卤代单-C1-4 -烷基苄基或苯基,卤素选自氯和溴,优选氯; 5位上最优选的取代基是对氯苯基。 1位的任选取代基选自C 1-4烷基和C 1-4烷氧基C 1-4烷基;优选在位置1上不存在取代基。在本发明中用作藤壶杀伤剂的最优选化合物是2-三氟甲基-3-溴-4-溴-4-氰基-5-对氯苯基吡咯。基于组合物的干物质的总重量,防污漆可包含0.5至9.9重量%的藤壶杀伤剂,优选1至6重量%,最优选1.5至4重量%。

著录项

  • 公开/公告号US6069189A

    专利类型

  • 公开/公告日2000-05-30

    原文格式PDF

  • 申请/专利权人 SIGMA COATINGS B.V.;

    申请/专利号US19970932673

  • 发明设计人 JOHANNES PETRUS KRAMER;MARCEL VOS;

    申请日1997-09-18

  • 分类号C08K5/34;

  • 国家 US

  • 入库时间 2022-08-22 01:37:05

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