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MOLECULAR ARRANGEMENT WITH A STRUCTURAL CONFIGURATION AND USE THEREOF FOR QUANTUM-MECHANICAL INFORMATION PROCESSING

机译:具有结构配置的分子排列及其在量子力学信息处理中的应用

摘要

Cage-type molecules differ significantly physically but are so chemically similar that until now it has been impossible to arrange them in relation to each other in controllable structures. According to the invention however, molecular arrangements with geometrically regular, periodic structural configurations with extremely precisely selectable intervals and angles can be produced in a self-organised manner by chemically modifying the molecular cages by specifically applying addends. Suitable type pairs (P') consisting of complementary and selective addends (A', B') are used. These addends (A', B'), which are generally bondable on two sides, are bonded with specific selectable sites of the cage molecules (A', B') with one end and form adducts (A2, B2) with the same. The other end is configured to be chemically highly selective so that the addends (A', B') bind exclusively with each other according to the chemical lock-and-key principle. By using stable, endohedral fullerenes (Z@Cx with X = 60) as cage-type molecules, filled with an electron spin carrying atom (Z), it is possible to produce spatially extremely precisely arranged electron spin systems for spin quantum computing, with very high detection sensitivity due to the use of electron spin resonance.
机译:笼型分子在物理上有显着差异,但在化学上是如此相似,以至于到目前为止,不可能将它们彼此相对地布置在可控制的结构中。然而,根据本发明,通过特别地施加加成物对分子笼进行化学修饰,可以以自组织的方式产生具有几何形状规则的周期性结构构型的分子排列,其具有极其精确的可选择的间隔和角度。使用由互补和选择性加数(A',B')组成的合适的类型对(P')。这些通常在两侧可结合的加成物(A',B')与笼形分子(A',B')的特定选择位点的一端结合并形成加合物(A2,B2)。另一端被配置为在化学上具有高度选择性,因此加成基团(A',B')根据化学锁定键原理相互唯一结合。通过使用稳定的,内表面的富勒烯(Z @ Cx,X = 60)作为笼型分子,填充有携带电子自旋的原子(Z),可以产生空间上极其精确排列的电子自旋系统,用于自旋量子计算,由于使用了电子自旋共振,因此具有很高的检测灵敏度。

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