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Use of medium strength acid as an isomerization catalyst of the epoxide which includes the carbonyl functional group in rank vis-a-vis epoxide

机译:使用中等强度的酸作为环氧化物的异构化催化剂,该环氧化物包括相对于环氧化物而言的羰基官能团

摘要

(57) Abstract As for this invention, in the aforementioned epoxide which is melted in the medium whose polarity is low in regard to the method of isomerizing the epoxide which possesses the carbonyl functional group in epoxide rank, the pKa (measurement) 0 - 3 is in water medium and solubility in benzene it is low at least in the 50C - the 150C, (it features that it operates acid the symbol d in Handbook of Chemistry and Physics " or ). This invention is applicable in organic synthesis.
机译:(57)<摘要>关于本发明,在使具有环氧基的羰基官能团的环氧化物异构化的方法中,在极性低的介质中熔融的上述环氧化物中,pKa(测定)为0。 -3在水介质中,并且在苯中的溶解度至少在50℃-150℃下较低(其特征在于它在《化学和物理手册》或“ d”中用酸操作)。本发明适用于有机合成。

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