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Propylene/ethylene/amp;agr;-olefin terpolymers and processes for the production thereof

机译:丙烯/乙烯/α-烯烃三元共聚物及其生产方法

摘要

A propylene/ethylene/&agr;-olefin terpolymer characterized in that;i) there is from 0.01 mol % to less than 15 mol % of a comonomer unit with a molar ratio of ethylene units/C4-C20 &agr;-olefin units being in the range of from 6.5×10−4 to 0.99, and from more than 85 mol % to not more than 99.99 mol % of a propylene unit with 2,1- and 1,3-propylene units being in the range of from 0 to 1 mol %, in a polymer chain determined by 13C-NMR spectroscopy;;ii) a weight average molecular weight (Mw) determined by GPC is in the range of from 40,000 to 1,000,000; and;iii) the amount of the component eluted in o-dichlorobenzene at a temperature of not higher than 40° C. is not more than 10 % by weight based on the total weight of the terpolymer and the amount of the component eluted in o-dichlorobenzene within the ±10° C. range of an elution peak temperature is not less than 75 % by weight based on the weight of the component eluted at a temperature of higher than 0° C.
机译:丙烯/乙烯/α-烯烃三元共聚物,其特征在于:i)以乙烯单元/ C 4 -的摩尔比计,存在0.01mol%至小于15mol%的共聚单体单元。 C 20 &α-烯烃单元的范围是6.5×10 负4 至0.99,范围从大于85 mol%到不大于99.99 mol通过 13 C-NMR光谱测定的聚合物链中,具有2,1-和1,3-丙烯单元的丙烯单元的百分比为0至1 mol%; ii )通过GPC测定的重均分子量(Mw)为40,000-1,000,000; iii)在不高于40℃的温度下在邻二氯苯中洗脱的组分的量;相对于三元共聚物的总重量和在邻二氯苯中洗脱的组分的量在≥10℃下,C。不大于10重量%。基于在高于0℃的温度下洗脱的组分的重量,洗脱峰温度的范围不小于75重量%; C。

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